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Pis'ma v Zh. Èksper. Teoret. Fiz., 2013, Volume 97, Issue 7, Pages 479–484 (Mi jetpl3395)  

This article is cited in 3 scientific papers (total in 3 papers)

CONDENSED MATTER

Electronic structure and indirect spin-spin interactions in bournonite (CuPbSbS3) according to antimony nuclear quadrupole resonance

A. Yu. Orlovaa, R. R. Gainova, A. V. Dooglava, I. N. Pen'kovb

a Institute of Physics, Kazan (Volga region) Federal University
b Institute of Geology and Petroleum Technologies, Kazan Federal University

Abstract: A complex sulfide CuPbSbS$_3$ (bournonite) has been studied by the nuclear quadrupole resonance on $^{121,123}$Sb. The temperature dependences of the spectroscopic and relaxation parameters in the temperature range of $10$-$295$ K have been obtained. The crystallochemical features of the environment of the two non-equivalent Sb positions in the unit cell have been revealed from the nuclear quadrupole resonance spectra. The existence of the lattice vibrations with the frequency $\omega=110$ cm$^{-1}$ has been demonstrated on the basis of the temperature dependence of the nuclear quadrupole resonance frequencies. Slow beats have been observed on the decay curve of the spin echo signal. Experimental data have been analyzed in order to reveal the existence of the indirect spin-spin interactions involving Sb atoms. The indirect spin-spin coupling constant has been estimated as $J=2.5 \pm 0.5$ kHz.

DOI: https://doi.org/10.7868/S0370274X13070084

Full text: PDF file (760 kB)
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English version:
Journal of Experimental and Theoretical Physics Letters, 2013, 97:7, 413–418

Bibliographic databases:

Document Type: Article
Received: 27.02.2013
Revised: 11.03.2013

Citation: A. Yu. Orlova, R. R. Gainov, A. V. Dooglav, I. N. Pen'kov, “Electronic structure and indirect spin-spin interactions in bournonite (CuPbSbS3) according to antimony nuclear quadrupole resonance”, Pis'ma v Zh. Èksper. Teoret. Fiz., 97:7 (2013), 479–484; JETP Letters, 97:7 (2013), 413–418

Citation in format AMSBIB
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\paper Electronic structure and indirect spin-spin interactions in bournonite (CuPbSbS3) according to antimony nuclear quadrupole resonance
\jour Pis'ma v Zh. \`Eksper. Teoret. Fiz.
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\vol 97
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\pages 479--484
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\crossref{https://doi.org/10.7868/S0370274X13070084}
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\crossref{https://doi.org/10.1134/S0021364013070096}
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    Citing articles on Google Scholar: Russian citations, English citations
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    This publication is cited in the following articles:
    1. Gainov R.R., Dooglav A.V., Vagizov F.G., Pen'kov I.N., Golovanevskiy V.A., Orlova A.Yu., Evlampiev Il'ya A., Klekovkina V.V., Klingelhoefer G., Ksenofontov V., Mozgova N.N., “Nqr/Nmr and Mossbauer Spectroscopy of Sulfides: Potential and Versatility”, Eur. J. Mineral., 25:4 (2013), 569–578  crossref  isi  elib  scopus
    2. Dong Y., Khabibullin A.R., Wei K., Salvador J.R., Nolas G.S., Woods L.M., “Bournonite Pbcusbs3: Stereochemically Active Lone-Pair Electrons That Induce Low Thermal Conductivity”, ChemPhysChem, 16:15 (2015), 3264–3270  crossref  isi  elib  scopus
    3. Kamienska-Trela K., “Applications of spin–spin couplings”, Nuclear Magnetic Resonance, Nuclear Magnetic Resonance, 44, ed. KamienskaTrela K., Royal Soc Chemistry, 2015, 170–234  crossref  isi  elib  scopus
  •       Pis'ma v Zhurnal ksperimental'noi i Teoreticheskoi Fiziki
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