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Pis'ma v Zh. Èksper. Teoret. Fiz., 2013, Volume 97, Issue 11, Pages 721–725 (Mi jetpl3435)  

This article is cited in 2 scientific papers (total in 2 papers)

CONDENSED MATTER

Hydrogen isotope exchange in proton-conducting oxides during proton and deuteron irradiation

V. B. Vykhodetsa, T. E. Kurennykha, V. P. Gorelovb, V. B. Balakirevab, E. V. Vykhodetsc, E. V. Obukhova

a Institute of Metal Physics, Ural Division of the Russian Academy of Sciences
b Institute of High-Temperature Electrochemistry, RAS
c Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg

Abstract: It has been found that during accelerator beam deuteron irradiation of a proton-conducting oxide containing protium H/D isotope exchange between beam ions and dissolved ions takes place. This isotope exchange was also observed during high-energy proton irradiation of the oxide containing dissolved deuterium atoms. These results provide evidence to a new type of hydrogen isotope exchange. Any appreciable effects of conjugate diffusion of hydrogen and oxygen ions and of the interface processes on the isotope exchange rate were eliminated. In this type of exchange the rate of replacement of H$^+$ by D$^+$ and of D$^+$ by H$^+$ was determined only by the properties of the crystal. The discovered effect was used in our study to obtain experimental data characterizing the dynamic and equilibrium behavior of hydrogen isotopes in the oxide BaZr$_{0.9}$Y$_{0.1}$O$_{3-\delta }$.

DOI: https://doi.org/10.7868/S0370274X13110040

Full text: PDF file (227 kB)
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English version:
Journal of Experimental and Theoretical Physics Letters, 2013, 97:11, 624–627

Bibliographic databases:

Document Type: Article
Received: 20.03.2013

Citation: V. B. Vykhodets, T. E. Kurennykh, V. P. Gorelov, V. B. Balakireva, E. V. Vykhodets, E. V. Obukhov, “Hydrogen isotope exchange in proton-conducting oxides during proton and deuteron irradiation”, Pis'ma v Zh. Èksper. Teoret. Fiz., 97:11 (2013), 721–725; JETP Letters, 97:11 (2013), 624–627

Citation in format AMSBIB
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\paper Hydrogen isotope exchange in proton-conducting oxides during proton and deuteron irradiation
\jour Pis'ma v Zh. \`Eksper. Teoret. Fiz.
\yr 2013
\vol 97
\issue 11
\pages 721--725
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\crossref{https://doi.org/10.7868/S0370274X13110040}
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\jour JETP Letters
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\vol 97
\issue 11
\pages 624--627
\crossref{https://doi.org/10.1134/S0021364013110106}
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    Citing articles on Google Scholar: Russian citations, English citations
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    This publication is cited in the following articles:
    1. Vykhodets V.B., Kurennykh T.E., Nefedova O.A., Gorelov V.P., Stroeva A.Yu., Balakireva V.B., Vykhodets E.V., Obukhov S.I., “Deuterium Diffusion in Proton Conductors La(0.9)Sr(0.1)Sco(3-Delta)and Bazr0.9Y0.1O3-Delta at Room Temperature”, Solid State Ion., 263 (2014), 152–156  crossref  isi  elib  scopus
    2. V. B. Vykhodets, O. A. Nefedova, E. V. Obukhov, T. E. Kurennykh, S. E. Danilov, E. V. Vykhodets, “Application of the nuclear reaction analysis online technique to study the diffusion of deuterium in metals”, JETP Letters, 107:4 (2018), 211–215  mathnet  crossref  crossref  isi  elib
  •       Pis'ma v Zhurnal ksperimental'noi i Teoreticheskoi Fiziki
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