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Pis'ma v Zh. Èksper. Teoret. Fiz., 2016, Volume 103, Issue 2, Pages 100–105 (Mi jetpl4839)  

This article is cited in 9 scientific papers (total in 9 papers)

CONDENSED MATTER

On reasons for the hysteresis of melting and crystallization of nanoparticles

V. M. Samsonov, S. A. Vasiliyev, I. V. Talyzin, Yu. A. Ryzhkov

Tver State University, Tver, 170100, Russia

Abstract: Molecular dynamics experiments for metal nanoclusters (gold, nickel, and aluminum) with the tight-binding potential have indicated that the melting temperature increases noticeably and the crystallization temperature decreases significantly with an increase in the absolute value of the heating and cooling rates, respectively. It has been concluded that the pronounced hysteresis of melting and crystallization is due primarily to nonequilibrium conditions of heating and cooling, but it is incompletely eliminated by reducing the rate of variation of the temperature. It has been found that the hysteresis of melting and crystallization corresponds at the structural level to a smooth crossover from the liquid state to the crystal one.

Funding Agency Grant Number
Ministry of Education and Science of the Russian Federation 3.2448.2014/K


DOI: https://doi.org/10.7868/S0370274X16020041

Full text: PDF file (566 kB)
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English version:
Journal of Experimental and Theoretical Physics Letters, 2016, 103:2, 94–99

Bibliographic databases:

Document Type: Article
Received: 20.04.2015
Revised: 12.10.2015

Citation: V. M. Samsonov, S. A. Vasiliyev, I. V. Talyzin, Yu. A. Ryzhkov, “On reasons for the hysteresis of melting and crystallization of nanoparticles”, Pis'ma v Zh. Èksper. Teoret. Fiz., 103:2 (2016), 100–105; JETP Letters, 103:2 (2016), 94–99

Citation in format AMSBIB
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    Citing articles on Google Scholar: Russian citations, English citations
    Related articles on Google Scholar: Russian articles, English articles

    This publication is cited in the following articles:
    1. Samsonov V.M. Bembel A.G. Samsonov T.E. Popov I.V. Vasilyev S.A., “On the Rheological Behavior of Nanoparticles in the Force Field of the Solid Surface: Nanotechnological Aspects”, Nanotechnol. Russ., 11:9-10 (2016), 553–561  crossref  isi  scopus
    2. A. G. Bembel, “On the Size Dependences of the Metallic Nanoparticle Evaporation and Sublimation Heats: Thermodynamics and Atomistic Modeling”, Russ. Phys. J., 59:10 (2017), 1567–1574  crossref  isi  scopus
    3. V. S. Baidyshev, Yu. Ya. Gafner, S. L. Gafner, L. V. Redel, “Thermal Stability of Pt Nanoclusters Interacting to Carbon Sublattice”, Phys. Solid State, 59:12 (2017), 2512–2518  crossref  isi  scopus
    4. V. M. Samsonov, S. A. Vasilyev, M. V. Samsonov, A. G. Bembel, A. V. Belotserkovskii, D. I. Rybakov, “Molecular Dynamics Search For Magic Numbers For Silver and Copper Clusters”, J. Struct. Chem., 58:7 (2017), 1377–1382  crossref  isi  scopus
    5. V. M. Samsonov, A. G. Bembel, I. V. Popov, S. A. Vasilyev, I. V. Talyzin, “Solid-State Wetting At the Nanoscale: Molecular Dynamics and Surface Diffusion Approach”, Surf. Innov., 5:3 (2017), 161–169  crossref  isi
    6. V. M. Samsonov, A. G. Bembel, A. Yu. Kartoshkin, S. A. Vasilyev, I. V. Talyzin, “Molecular dynamics and thermodynamic simulations of segregation phenomena in binary metal nanoparticles”, J. Therm. Anal. Calorim., 133:2 (2018), 1207–1217  crossref  isi  scopus
    7. S. A. Guchenko, V. M. Yurov, V. Ch. Laurinas, S. S. Kasymov, “About the temperature of melting of metallic nanoparticles”, Bull. Univ. Karaganda-Phys., 3:91 (2018), 16–28  isi
    8. V. M. Samsonov, N. Yu. Sdobnyakov, V. S. Myasnichenko, I. V. Talyzin, V. V. Kulagin, S. A. Vasilyev, A. G. Bembel, A. Yu. Kartoshkin, D. N. Sokolov, “A comparative analysis of the size dependence of the melting and crystallization temperatures in silver nanoparticles via the molecular dynamics and monte-carlo methods”, J. Surf. Ingestig., 12:6 (2018), 1206–1209  crossref  isi  scopus
    9. Samsonov V.M., Talyzin I.V., Kartoshkin A.Yu., Vasilyev S.A., “Surface Segregation in Binary Cu-Ni and Au-Co Nanoalloys and the Core-Shell Structure Stability/Instability: Thermodynamic and Atomistic Simulations”, Appl. Nanosci., 9:1 (2019), 119–133  crossref  isi  scopus
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