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Nelin. Dinam., 2017, Volume 13, Number 2, Pages 195–206 (Mi nd560)  

This article is cited in 2 scientific papers (total in 2 papers)

Original papers

Solution gas and solution crystal oscillatory phase transitions in the drops of aqueous solutions with one crystallizable component

V. B. Fedoseev

Razuvaev Institute of Organometallic Chemistry of RAS, ul. Tropinina 49, GSP-445, Nizhny Novgorod, 603950, Russia

Abstract: Long-term aperiodic oscillatory phase transitions of gas solution and solution crystal have been reproduced experimentally in the ensemble of aqueous droplets with a dissolved component. The new observations can simplify the dynamic model of phase transitions of the oscillating mode considered before. It reduces the number of independent variables and the need to consider the formation of metastable phases. The model establishes a relation between the speed and direction of solvent flow in the gas and the vapor pressure in the drop neighborhood, temperature of the drop, the rate of change in temperature, the rate of change in volumes of the drop and the crystal. The analysis has revealed that the presence of crystalline phases in the system causes at least two singularities (bifurcations) of the chemical potential of the volatile component with respect to its quantities in the drop.

Keywords: phase transitions, oscillation, evaporation, condensation, crystallization, drop of solution

Funding Agency Grant Number
Russian Science Foundation 15-13-00137


DOI: https://doi.org/10.20537/nd1702004

Full text: PDF file (2131 kB)
References: PDF file   HTML file

UDC: 544.431.8+544.015.4
MSC: 92E99, 80A20, 74A50, 82C26, 70K50
Received: 07.01.2017
Accepted:15.05.2017

Citation: V. B. Fedoseev, “Solution gas and solution crystal oscillatory phase transitions in the drops of aqueous solutions with one crystallizable component”, Nelin. Dinam., 13:2 (2017), 195–206

Citation in format AMSBIB
\Bibitem{Fed17}
\by V.~B.~Fedoseev
\paper Solution gas and solution crystal oscillatory phase transitions in the drops of aqueous solutions with one crystallizable component
\jour Nelin. Dinam.
\yr 2017
\vol 13
\issue 2
\pages 195--206
\mathnet{http://mi.mathnet.ru/nd560}
\crossref{https://doi.org/10.20537/nd1702004}
\elib{https://elibrary.ru/item.asp?id=29443377}


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    Citing articles on Google Scholar: Russian citations, English citations
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    This publication is cited in the following articles:
    1. V. B. Fedoseev, A. V. Shishulin, “Shape effect in layering of solid solutions in small volume: bismuth-antimony alloy”, Phys. Solid State, 60:7 (2018), 1398–1404  crossref  isi  scopus
    2. V. B. Fedoseev, E. N. Fedoseeva, “Formation of bi-and polymodal distributions and the non-Ostwald behavior of disperse systems”, J. Eng. Phys. Thermophys., 92:5 (2019), 1191–1200  crossref  isi  scopus
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