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Kvantovaya Elektronika, 2001, Volume 31, Number 6, Pages 483–488 (Mi qe1985)  

This article is cited in 4 scientific papers (total in 4 papers)

Femtosecond technologies

Control of elementary chemical reactions by femtosecond light pulses

O. M. Sarkisov, A. N. Petrukhin, F. E. Gostev, A. A. Titov

N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow

Abstract: Essentially new approaches are proposed for controlling the yield of products of a chemical reaction by femto-second laser pulses. The main attention is paid to the method based on the change in phase characteristics of femtosecond pulses. The quantum yield of the product NH(c1Π) upon multiphoton photodissociation of ammonium in gas is shown to increase by a factor of twelve with chirp variation from –1250 fs2 to 2000 fs2. It is demonstrated by the example of two-proton transfer in [2,2'-bipyridyl],3,3'-diol in solution that the approach based on the variation in phase characteristics of a pump femtosecond pulse can be also used for controlling reactions in solutions.

Full text: PDF file (218 kB)

English version:
Quantum Electronics, 2001, 31:6, 483–488

Bibliographic databases:

PACS: 82.53.-k, 82.50.Nd, 82.50.Pt
Received: 21.03.2001

Citation: O. M. Sarkisov, A. N. Petrukhin, F. E. Gostev, A. A. Titov, “Control of elementary chemical reactions by femtosecond light pulses”, Kvantovaya Elektronika, 31:6 (2001), 483–488 [Quantum Electron., 31:6 (2001), 483–488]

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    This publication is cited in the following articles:
    1. A. L. Fradkov, Phys. Usp., 48:2 (2005), 103–127  mathnet  crossref  crossref  adsnasa  isi
    2. Mishra A.K., Karni O., Eisenstein G., Opt. Express, 23:23 (2015), 29940–29953  crossref  isi  scopus
    3. Barykov V.Yu., Ivanov A.I., Russ. J. Phys. Chem. A, 90:2 (2016), 491–497  crossref  isi  scopus
    4. V. Yu. Barykov, A. V. Tkacheva, A. I. Ivanov, Vestn. Volgogr. gos. un-ta. Ser. 1, Mat. Fiz., 2016, no. 2(33), 70–83  mathnet  crossref
  • Квантовая электроника Quantum Electronics
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