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Usp. Khim., 1966, Volume 35, Issue 6, Pages 1102–1128 (Mi rcr1997)  

Outer-sphere interaction in aqueous solutions of complex compounds

V. E. Mironov

Leningrad Technological Institute

Abstract: CONTENTS
I. Introduction 455
II. Standardisation of conditions for studying outer-sphere association in aqueous solutions of complex compounds 456
III. Procedure for calculating the outer-sphere association constants for labile complexes 457
IV. The most widely used methods for determining outer-sphere association constants 459
V. Outer-sphere association and the law of mass action 459
VI. Some rules of outer-sphere association 461
VII. Prediction of constants for the association of anionic complexes with alkali metal cations 465
VIII. Comparison of outer-sphere and inner-sphere association constants 465
IX. Complex formation with allowance for associative interaction with the ions of the salt medium 466


Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=1488

English version:
Russian Chemical Reviews, 1966, 35:6, 455–469

Document Type: Article
UDC: 541.49:541.571.53

Citation: V. E. Mironov, “Outer-sphere interaction in aqueous solutions of complex compounds”, Usp. Khim., 35:6 (1966), 1102–1128; Russian Chem. Reviews, 35:6 (1966), 455–469

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