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Usp. Khim., 1974, Volume 43, Issue 1, Pages 3–34 (Mi rcr2680)  

Catalysis of Symmetry-disallowed Reactions

V. I. Labunskayaa, A. D. Shebaldovaa, M. L. Khidekel'b

a Saratov State University named after N. G. Chernyshevsky
b Institute of Chemical Physics of the USSR Academy of Sciences, Moscow

Abstract: Opportunities for applying the principle of the conservation of orbital symmetry to catalytic processes are surveyed. Current views on the role of a transition metal in the catalysis of symmetry-disallowed reactions are reported, and possible mechanisms are discussed. Close attention is paid to the correlation of the catalytic activity of metal-containing catalysts with the electron configuration of the transition metal, the structure of the complex, and the nature of the ligands. Examples of catalytic reactions disallowed by the Woodward–Hoffmann rules – valency isomerisation of hydrocarbons, hydrogenation and disproportionation of alkenes, cyclo-oligomerisation – are considered in the light of ideas on concerted and stepwise mechanisms. A list of 137 references is included.

Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=1785

English version:
Russian Chemical Reviews, 1974, 43:1, 1–16

Document Type: Article
UDC: 541.128

Citation: V. I. Labunskaya, A. D. Shebaldova, M. L. Khidekel', “Catalysis of Symmetry-disallowed Reactions”, Usp. Khim., 43:1 (1974), 3–34; Russian Chem. Reviews, 43:1 (1974), 1–16

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