Silicon Tetrafluoride Adducts
A. A. Ènnan, B. M. Kats
I. I. Mechnikov Odessa State University, Department of Chemistry
The review deals with the compositions, properties, structures, and thermodynamics of silicon tetrafluoride adducts with organic molecules containing electron-donating nitrogen, oxygen, phosphorus, or sulphur atoms. Particular attention has been paid to reactions involving the conversion of the adducts of nitrogen-containing bases into fluorine-containing compounds with a covalent silicon–nitrogen bond. The comparative estimates of the electron-accepting properties of silicon tetrafluoride and other silicon tetrahalides obtained by different workers are discussed.
The bibliography includes 126 references.
Russian Chemical Reviews, 1974, 43:7, 539–550
A. A. Ènnan, B. M. Kats, “Silicon Tetrafluoride Adducts”, Usp. Khim., 43:7 (1974), 1186–1206; Russian Chem. Reviews, 43:7 (1974), 539–550
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