This article is cited in 1 scientific paper (total in 1 paper)
The Reactions of Hydrocarbons on Membrane Catalysts
V. M. Gryaznova, V. S. Smirnovb
a Peoples Friendship University of Russia
b A. V. Topchiev Institute of Petrochemical Synthesis of the Academy of Sciences of the USSR, Moscow
The reactions of different classes of hydrocarbons on catalysts selectively permeable with respect to hydrogen are considered. The possibilities of membrane catalysts to increase the rate and selectivity of reactions, to obtain incomplete hydrogenation products, and to decrease the competition between the adsorption of the substance hydrogenated and hydrogen are demonstrated. The coupling of reactions on membrane catalysts whereby it is possible to achieve a reaction, which does not occur spontaneously, as a result of the decrease of the free energy of the coupled reaction when the substance common to the two reactions passes through the membrane catalyst is discussed.
The bibliography includes 135 references.
Russian Chemical Reviews, 1974, 43:10, 821–834
V. M. Gryaznov, V. S. Smirnov, “The Reactions of Hydrocarbons on Membrane Catalysts”, Usp. Khim., 43:10 (1974), 1716–1738; Russian Chem. Reviews, 43:10 (1974), 821–834
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Basov N.L. Ermilova M.M. Orekhova N.V. Yaroslavtsev A.B., “Membrane Catalysis in the Dehydrogenation and Hydrogen Production Processes”, Russ. Chem. Rev., 82:4 (2013), 352–368
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