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Usp. Khim., 2007, Volume 76, Issue 9, Pages 907–926 (Mi rcr304)  

This article is cited in 34 scientific papers (total in 34 papers)

Chemistry of metallasiloxanes. Current trends and new concepts

M. M. Levitsky, B. G. Zavin, A. N. Bilyachenko

A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow

Abstract: The current status of the chemistry of metallasiloxanes is surveyed. Synthetic methods affording the metallasiloxane fragments and specific transformations of metallasiloxanes governed by the coordination properties of the metal site are analysed. The emphasis is placed onto the formation of compounds with the metallasiloxane fragments and rearrangements of these fragments. Principles of the design of catalytic systems based on metallasiloxanes, in particular, containing low-coordinated metal sites, are generalised.

Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=3691

English version:
Russian Chemical Reviews, 2007, 76:9, 847–866

Bibliographic databases:

Document Type: Article
Received: 15.12.2006

Citation: M. M. Levitsky, B. G. Zavin, A. N. Bilyachenko, “Chemistry of metallasiloxanes. Current trends and new concepts”, Usp. Khim., 76:9 (2007), 907–926; Russian Chem. Reviews, 76:9 (2007), 847–866

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    Citing articles on Google Scholar: Russian citations, English citations
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    This publication is cited in the following articles:
    1. M. M. Levitsky, B. G. Zavin, A. N. Bilyachenko, “ChemInform Abstract: Chemistry of Metallasiloxanes. Current Trends and New Concepts”, ChemInform, 39:6 (2008)  crossref
    2. Levitsky M.M., Zavin B.G., Bilyachenko A.N., Morgunov R.B., Kurganova E.V., Ovanesyan N.S., Pol'shin E.V., “Magnetic Properties of Structurally Organized Sodium Ferrophenylsiloxane”, Russ. Chem. Bull., 57:8 (2008), 1630–1632  crossref  isi  elib  scopus
    3. Anja Edelmann, Steffen Blaurock, Cristian Hrib, Frank T. Edelmann, “Double InMe2 insertion into a 12-membered Si4O6Li2 inorganic ring system coordinated to praseodymium”, Journal of Organometallic Chemistry, 695:7 (2010), 1026  crossref  isi  scopus
    4. N A Tebeneva, A M Muzafarov, E S Trofimchuk, M A Chuev, S K Dedushenko, L A Kulikov, Yu D Perfiliev, “Moessbauer study of tris-(methyldietoxysiloxy)iron and its derivatives”, J Phys Conf Ser, 217 (2010), 012040  crossref  adsnasa  isi  elib  scopus
    5. Volker Lorenz, Anja Edelmann, Stephan Gießmann, Cristian G. Hrib, Steffen Blaurock, Frank T. Edelmann, “Disiloxanediolates and Metallasilsesquioxanes of the Rare Earth Elements ”, Z anorg allg Chem, 636:12 (2010), 2172  crossref  isi  scopus
    6. Volker Lorenz, Anja Edelmann, Steffen Blaurock, Cristian Hrib, Frank T. Edelmann, “New lanthanide(III) disiloxanediolates: Syntheses and structures”, Comptes Rendus Chimie, 13:6-7 (2010), 577  crossref  isi  scopus
    7. Borisov Yu.A., Papkov V.S., Sergienko N.V., Zavin B.G., Buzin M.I., “Si-C Bond Strength in Cage-Like Methylsilsesquioxanes and Methyl-Bearing Metalosilsesquioxanes Estimated From Dft Calculations”, Russ. Chem. Bull., 59:5 (2010), 881–885  crossref  isi  elib  scopus
    8. Clemens Krempner, “Role of Siloxides in Transition Metal Chemistry and Homogeneous Catalysis”, Eur. J. Inorg. Chem, 2011:11 (2011), 1689  crossref  isi  scopus
    9. Zavin B.G., Sergienko N.V., Cherkun N.V., Bilyachenko A.N., Starikova O.M., Korlyukov A.A., Dronova M.S., Levitskii M.M., Timofeeva G.I., “Synthesis of Bimetallic Cage-Like Metalloorganosiloxanes From Polymeric Metallosiloxanes”, Russ. Chem. Bull., 60:8 (2011), 1647–1650  crossref  isi  elib  scopus
    10. Bilyachenko A.N., Dronova M.S., Korlyukov A.A., Levitsky M.M., Antipin M.Yu., Zavin B.G., “Cage-Like Manganesephenylsiloxane with an Unusual Structure”, Russ. Chem. Bull., 60:8 (2011), 1762–1765  crossref  isi  elib  scopus
    11. A.N.. Bilyachenko, M.S.. Dronova, A.I.. Yalymov, A.A.. Korlyukov, L.S.. Shul'pina, “Binuclear Cage-Like Copper(II) Silsesquioxane (“Cooling Tower”) - Its High Catalytic Activity in the Oxidation of Benzene and Alcohols”, Eur. J. Inorg. Chem, 2013:30 (2013), 5240  crossref  isi  scopus
    12. Zolotareva N.V. Semenov V.V., “Beta-Diketones and Their Derivatives in Sol-Gel Processes”, Russ. Chem. Rev., 82:10 (2013), 964–987  mathnet  crossref  isi  elib  scopus
    13. M.S.. Dronova, A.N.. Bilyachenko, A.I.. Yalymov, Yu.N.. Kozlov, L.S.. Shul'pina, “Solvent-controlled synthesis of tetranuclear cage-like copper(ii) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation with peroxides”, Dalton Trans, 43:2 (2014), 872  crossref  isi  elib  scopus
    14. Volker Lorenz, C.G.. Hrib, P.G.. Jones, F.T.. Edelmann, “Synthesis and structure of a heterotrimetallic (Li/Er/In), heptacyclic metallasiloxane cage compound”, Inorganic Chemistry Communications, 49 (2014), 37  crossref  zmath  isi  scopus
    15. Janek Rausch, Volker Lorenz, C.G.. Hrib, Vanessa Frettlöh, Matthias Adlung, “Heterometallic Europium Disiloxanediolates: Synthesis, Structural Diversity, and Photoluminescence Properties”, Inorg. Chem, 2014, 1410200928  crossref  isi  scopus
    16. Asim Ali, Mirko Langer, Volker Lorenz, C.G.. Hrib, Liane Hilfert, “Synthesis and Structure of Hexaphenyltrisiloxanediolates of Sodium, Titanium, and Iron”, Journal of Organometallic Chemistry, 2014  crossref  isi  scopus
    17. Maria Nowacka, Anna Kowalewska, Krystyna Gadzinowska, “Alkali-Metal-Directed Hydrolytic Condensation of 3-Mercaptopropyltrimethoxysilane”, Silicon, 2014  crossref  isi  scopus
    18. M.M.. Vinogradov, Yu.N.. Kozlov, A.N.. Bilyachenko, D.S.. Nesterov, L.S.. Shul'pina, “Alkane oxidation with peroxides catalyzed by cage-like copper(ii) silsesquioxanes”, New J. Chem, 39:1 (2014), 187  crossref  isi  scopus
    19. A.N.. Bilyachenko, M.S.. Dronova, A.I.. Yalymov, Frédéric Lamaty, Xavier Bantreil, “Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies”, Chem. Eur. J, 2015, n/a  crossref  isi  scopus
    20. M.M.. Levitsky, A.N.. Bilyachenko, “Modern Concepts And Methods In The Chemistry Of Polyhedral Metallasiloxanes”, Coordination Chemistry Reviews, 2015  crossref  isi  scopus
    21. C.P.. Richers, J.A.. Bertke, D.L.. Gray, T.B.. Rauchfuss, “Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ3-methanolato-tetra-μ2-methanolato-tetrairon(III)”, Acta Crystallogr E Cryst Commun, 71:8 (2015), 976  crossref  isi  scopus
    22. D. A. Sapozhnikov, Ya. S. Vygodskii, “Achievements in polycondensation and condensation polymers”, Polym. Sci. Ser. B, 57:4 (2015), 275  crossref  isi  elib  scopus
    23. Haj S.B., Dietz Ch., Lutter M., Jurkschat K., “Cyclo-Stannasiloxanes Containing Both Oxygen Atoms and Methylene Moieties Within the Ring and Formation of Related Organotin Oxo Clusters”, Organometallics, 34:23 (2015), 5555–5565  crossref  isi  scopus
    24. Ehle S., Lorenz V., Liebing Ph., Hilfert L., Edelmann F.T., “Synthesis and structural characterization of two complex tantalum(V) siloxides”, Inorg. Chem. Commun., 74 (2016), 82–85  crossref  isi  scopus
    25. Levitsky M.M., Yalymov A.I., Kulakova A.N., Petrov A.A., Bilyachenko A.N., “Cage-like metallasilsesquioxanes in catalysis: A review”, J. Mol. Catal. A-Chem., 426:B, SI (2017), 297–304  crossref  isi  scopus
    26. Giessmann S., Lorenz V., Liebing Ph., Hilfert L., Fischer A., Edelmann F.T., “Synthesis and structural study of new metallasilsesquioxanes of potassium and uranium”, Dalton Trans., 46:8 (2017), 2415–2419  crossref  isi  scopus
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    29. Rausch J., Liebing Ph., Lorenz V., Hrib C.G., Ali A., Gross P., Hilfert L., Busse S., Edelmann F.T., “Synthesis and Structural Characterization of Homo- and Heterometallic Li and Li/Ln Disiloxanediolate Complexes”, Z. Anorg. Allg. Chem., 643:23, SI (2017), 1920–1928  crossref  isi  scopus
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