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Usp. Khim., 2007, Volume 76, Issue 9, Pages 927–944 (Mi rcr305)  

This article is cited in 21 scientific papers (total in 21 papers)

Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives

V. Ya. Basevich, S. M. Frolov

N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow

Abstract: Experimental and calculated data on the kinetics of ′blue' flame observed in the gas-phase oxidation and combustion of hydrocarbons and their derivatives are considered. It is shown that blue flames arise due to the decomposition of hydrogen peroxide that forms in the oxidation of hydrocarbons. They manifest themselves by light emission, are identified by partial heat release (the appearance of a step in the time dependences of temperature and pressure observed in closed-vessel experiments) and propagate as conventional hot flames.

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Russian Chemical Reviews, 2007, 76:9, 867–884

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Document Type: Article
Received: 07.03.2007

Citation: V. Ya. Basevich, S. M. Frolov, “Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives”, Usp. Khim., 76:9 (2007), 927–944; Russian Chem. Reviews, 76:9 (2007), 867–884

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    This publication is cited in the following articles:
    1. V. Ya. Basevich, S. M. Frolov, “ChemInform Abstract: Kinetics of “Blue” Flames in the Gas-Phase Oxidation and Combustion of Hydrocarbons and Their Derivatives”, ChemInform, 39:6 (2008)  crossref
    2. Basevich V.Ya., Belyaev A.A., Posvyanskii V.S., Frolov S.M., “Mechanism of the Oxidation and Combustion of Normal Paraffin Hydrocarbons: Transition From C-1-C-6 to C7H16”, Russ. J. Phys. Chem. B, 4:6 (2010), 985–994  crossref  isi
    3. Sharipov G.L. Abdrakhmanov A.M., “Sonochemiluminescence of Aromatic Hydrocarbons”, Russ. Chem. Bull., 59:9 (2010), 1680–1685  crossref  isi  elib  scopus
    4. M.A.. Deminsky, I.V.. Kochetov, A.P.. Napartovich, S.B.. Leonov, “Modeling of Plasma Assisted Combustion in Premixed Supersonic Gas Flow”, International Journal of Hypersonics, 1:4 (2010), 209  crossref
    5. S.M. Frolov, V.S. Ivanov, B. Basara, M. Suffa, “Numerical simulation of flame propagation and localized preflame autoignition in enclosures”, Journal of Loss Prevention in the Process Industries, 2011  crossref  isi  scopus
    6. V. S. Arutyunov, L. N. Strekova, “Kinetic features and technological perspectives of the partial oxidation of light alkanes”, Russ. J. Phys. Chem. B, 6:4 (2012), 486  crossref  isi  elib  scopus
    7. Frolov S.M., Dubrovskii A.V., Ivanov V.S., “Three-Dimensional Numerical Simulation of the Operation of the Rotating-Detonation Chamber”, Russ. J. Phys. Chem. B, 6:2 (2012), 276–288  crossref  isi  elib  scopus
    8. S. M. Frolov, A. V. Dubrovskii, V. S. Ivanov, “Three-dimensional numerical simulation of the operation of a rotating-detonation chamber with separate supply of fuel and oxidizer”, Russ. J. Phys. Chem. B, 7:1 (2013), 35  crossref  isi  elib  scopus
    9. V. Ya. Basevich, A. A. Belyaev, V. S. Posvyanskii, S. M. Frolov, “Mechanisms of the oxidation and combustion of normal paraffin hydrocarbons: Transition from C1–C10 to C11–C16”, Russ. J. Phys. Chem. B, 7:2 (2013), 161  crossref  isi  elib  scopus
    10. S.M. Frolov, M. Emans, V.S. Ivanov, B. Basara, V.V. Leshevich, “3D simulation of hydrogen ignition in a rapid compression machine”, Journal of Loss Prevention in the Process Industries, 2013  crossref  isi  scopus
    11. E.A. Filimonova, “Discharge effect on the negative temperature coefficient behaviour and multistage ignition in C3H8-air mixture”, J. Phys. D: Appl. Phys, 48:1 (2015), 015201  crossref  isi  scopus
    12. A. V. Dubrovskii, V. S. Ivanov, S. M. Frolov, “Three-dimensional numerical simulation of the operation process in a continuous detonation combustor with separate feeding of hydrogen and air”, Russ. J. Phys. Chem. B, 9:1 (2015), 104  crossref  isi  elib  scopus
    13. V. Ya. Basevich, A. A. Belyaev, S. N. Medvedev, V. S. Posvyanskii, S. M. Frolov, “Detailed kinetic mechanism of the multistage oxidation and combustion of isobutane”, Russ. J. Phys. Chem. B, 9:2 (2015), 268  crossref  isi  elib  scopus
    14. Artem'ev K.V., Berezhetskaya N.K., Kossyi I.A., Misakyan M.A., Popov N.A., Tarasova N.M., “Processes of Chemoionization in the Course of Inflammation of a Methane-Oxygen Mixture By a High-Current Gliding Surface Discharge in a Closed Chamber”, Plasma Phys. Rep., 41:5 (2015), 415–425  crossref  isi  scopus
    15. Frolov S.M., Aksenov V.S., Dubrovskii A.V., Ivanov V.S., Shamshin I.O., “Energy Efficiency of a Continuous-Detonation Combustion Chamber”, Combust. Explos., 51:2 (2015), 232–245  crossref  isi  elib  scopus
    16. K. V. Artem'ev, N. K. Berezhetskaya, S. Yu. Kazantsev, N. G. Kononov, I. A. Kossyi, “Fast combustion waves and chemi-ionization processes in a flame initiated by a powerful local plasma source in a closed reactor”, Phil. Trans. R. Soc. A, 373:2048 (2015), 20140334  crossref  isi  scopus
    17. Dubrovskii A.V., Ivanov V.S., Zangiev A.E., Frolov S.M., “Three-dimensional numerical simulation of the characteristics of a ramjet power plant with a continuous-detonation combustor in supersonic flight”, Russ. J. Phys. Chem. B, 10:3 (2016), 469–482  crossref  isi  scopus
    18. Frolov S.M., Basevich V.Ya., Medvedev S.N., “Modeling of Low-temperature oxidation and combustion of droplets”, Dokl. Phys. Chem., 470:2 (2016), 150–153  crossref  isi  scopus
    19. Frolov S.M., Dubrovskii A.V., Ivanov V.S., “Three-dimensional numerical simulation of a continuously rotating detonation in the annular combustion chamber with a wide gap and separate delivery of fuel and oxidizer”, Progress in Propulsion Physics (Munich, Germany, July 4-8, 2013), eds. Calabro M., DeLuca L., Frolov S., Galfetti L., Haidn O., E D P Sciences, 2016, 375–388  crossref  isi
    20. Obukhov A.E., “Optical Spectroscopy and the Structure of Polyfunctional Hydrocarbon Compounds and Oil Products”, Opt. Spectrosc., 124:5 (2018), 696–702  crossref  isi  scopus
    21. Frolov S.M., Basevich V.Ya., Medvedev S.N., Frolov F.S., “Low-Temperature Flameless Combustion of a Large Drop of N-Dodecane Under Microgravity Conditions”, Russ. J. Phys. Chem. B, 12:2 (2018), 245–257  crossref  isi  scopus
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