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Усп. хим., 2007, том 76, выпуск 11, страницы 1122–1144 (Mi rcr314)  

Эта публикация цитируется в 49 научных статьях (всего в 49 статьях)

Неметаллоценовые металлоорганические производные редкоземельных элементов: синтез, строение и применение в катализе превращений ненасыщенных субстратов

А. А. Трифонов

Институт металлоорганической химии им. Г. А. Разуваева РАН, г. Нижний Новгород

Аннотация: Проведен анализ пост-металлоценового периода развития химии металлоорганических соединений редкоземельных металлов. Рассмотрены синтез, строение и реакционная способность комплексов, содержащих связи металл–углерод и металл–водород и стабилизированных N-, P- и O-донорными лигандами, а также их каталитическая активность в реакциях полимеризации, гидроаминирования, гидросилилирования и гидроборирования алкенов.
Библиография — 139 ссылок.

Полный текст: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=3693

Англоязычная версия:
Russian Chemical Reviews, 2007, 76:11, 1051–1072

Реферативные базы данных:

Тип публикации: Статья
Поступила в редакцию: 09.01.2007

Образец цитирования: А. А. Трифонов, “Неметаллоценовые металлоорганические производные редкоземельных элементов: синтез, строение и применение в катализе превращений ненасыщенных субстратов”, Усп. хим., 76:11 (2007), 1122–1144; Russian Chem. Reviews, 76:11 (2007), 1051–1072

Образцы ссылок на эту страницу:
  • http://mi.mathnet.ru/rcr314
  • http://mi.mathnet.ru/rus/rcr/v76/i11/p1122

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    Citing articles on Google Scholar: Russian citations, English citations
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    Эта публикация цитируется в следующих статьяx:
    1. A. A. Trifonov, “ChemInform Abstract: Non-Metallocene Rare-Earth Organometallic Derivatives: Synthesis, Structure and Application in the Catalysis of Transformations of Unsaturated Substrates”, ChemInform, 39:20 (2008)  crossref
    2. Aillaud I., Lyubov D., Collin J., Guillot R., Hannedouche J., Schulz E., Trifonov A., “Chiral Amido Alkyl Rare Earth Complexes: a New Family of Asymmetric Intramolecular Hydroamination Catalysts”, Organometallics, 27:22 (2008), 5929–5936  crossref  isi  elib  scopus
    3. Lyubov D.M., Doering Ch., Fukin G.K., Cherkasov A.V., Shavyrin A.S., Kempe R., Trifonov A.A., “Selective Assembly of Trinuclear Rare-Earth Alkyl Hydrido Clusters Supported by Amidopyridinate Ligands”, Organometallics, 27:13 (2008), 2905–2907  crossref  isi  elib  scopus
    4. Lyubov D.M., Fukin G.K., Cherkasov A.V., Shavyrin A.S., Trifonov A.A., Luconi L., Bianchini C., Meli A., Giambastiani G., “Selective SIGMA-Bond Metathesis in Alkyl-Aryl and Alkyl-Benzyl Yttrium Complexes. New Aryl- and Benzyl-Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands”, Organometallics, 28:4 (2009), 1227–1232  crossref  isi  elib  scopus
    5. Skvortsov G.G., Lyubov D.M., Yakovenko M.V., Fukin G.K., Cherkasov A.V., Trifonov A.A., “Guanidinate Derivatives of Rare-Earth Metals. the Synthesis, Properties, and Molecular Structures of the Complexes ((Me3Si)(2)Nc(Npri)(2))(3)Nd, ((Me3Si)(2)Nc(Ncy)(2))(3)Lu, and ((Me3Si)(2)Nc(Npri)(2))(2)Hc(Npri)(2))Nd”, Russ. Chem. Bull., 58:6 (2009), 1126–1131  crossref  isi  elib  scopus
    6. Sophie Putzien, Oskar Nuyken, Fritz E. Kühn, “Functionalized polysilalkylene siloxanes (polycarbosiloxanes) by hydrosilylation—Catalysis and synthesis”, Progress in Polymer Science, 35:6 (2010), 687  crossref  isi  scopus
    7. Lapo Luconi, Dmitrii M. Lyubov, Claudio Bianchini, Andrea Rossin, Cristina Faggi, Georgii K. Fukin, Anton V. Cherkasov, Andrei S. Shavyrin, Alexander A. Trifonov, Giuliano Giambastiani, “Yttrium-Amidopyridinate Complexes: Synthesis and Characterization of Yttrium-Alkyl and Yttrium-Hydrido Derivatives”, Eur J Inorg Chem, 2010:4 (2010), 608  crossref  isi  scopus
    8. Rhett Kempe, “Rare Earth Polymerization Catalysts Supported by Bulky Aminopyridinato Ligands”, Z anorg allg Chem, 636:12 (2010), 2135  crossref  isi  scopus
    9. Marina V. Yakovenko, Anton V. Cherkasov, Georgy K. Fukin, Dongmei Cui, Alexander A. Trifonov, “Lanthanide Complexes Coordinated by a Dianionic Bis(amidinate) Ligand with a Rigid Naphthalene Linker”, Eur J Inorg Chem, 2010:21 (2010), 3290  crossref  isi  scopus
    10. Grigorii G. Skvortsov, Alexei O. Tolpyguin, Georgy K. Fukin, Anton V. Cherkasov, Alexander A. Trifonov, “Dinuclear Chlorido-, Alkyl(chlorido)-, and Hydridoyttrium Complexes Supported by μ-Bridging-Silyl-Linked Bis(amidinate) Ligands”, Eur. J. Inorg. Chem, 2010:11 (2010), 1655  crossref  isi  scopus
    11. Lyubov D.M., Shavyrin A.S., Kurskii Yu.A., Trifonov A.A., “Hydrosilylation of Non-1-Ene with Phenylsilane in the Presence of Yttrium and Lutetium Bisguanidinate Hydride Complexes”, Russ. Chem. Bull., 59:9 (2010), 1765–1770  crossref  isi  elib  scopus
    12. Dmitrii M. Lyubov, Christian Döring, Sergei Yu. Ketkov, Rhett Kempe, Alexander A. Trifonov, “Selective Protonation of the YC Bond in Trinuclear Yttrium Alkyl-Hydrido Clusters and Formation of the Cationic Polyhydrido Core”, Chem. Eur. J, 2011, n/a  crossref  isi  scopus
    13. Mikhail A. Sinenkov, Georgy K. Fukin, Anton V. Cherkasov, Noureddine Ajellal, Thierry Roisnel, Francesca M. Kerton, Jean-François Carpentier, Alexander A. Trifonov, “Neodymium borohydride complexes supported by diamino-bis(phenoxide) ligands: diversity of synthetic and structural chemistry, and catalytic activity in ring-opening polymerization of cyclic esters”, New J. Chem, 35:1 (2011), 204  crossref  isi  scopus
    14. Aillaud I., Olier C., Chapurina Yu., Collin J., Schulz E., Guillot R., Hannedouche J., Trifonov A., “Alkyl Complexes of Lanthanum and Samarium Supported by a Chiral Binaphthylamido Ligand. Syntheses, Structures, and Catalytic Activity in Hydroamination of Amino-1,3-Dienes”, Organometallics, 30:12 (2011), 3378–3385  crossref  isi  elib  scopus
    15. Rad'kov V.Yu., Skvortsov G.G., Fukin G.K., Lyssenko K.A., Antipin M.Yu., Trifonov A.A., “New Potentially Tridentate Amidinate Ligand (O-Meoc6H4Nc(Ph)N(Sime3))(-). Synthesis and Molecular Structures of Amidinate Complexes of Lithium [(O-Meoc6H4Nc(Ph)N(Sime3))Li](2) and Yttrium [(O-Meoc6H4Nc(Ph)N(Sime3))Ycl2(Thf)(2)](2)”, Russ. Chem. Bull., 60:5 (2011), 803–808  crossref  isi  scopus
    16. Vassily Yu. Rad'kov, Grigorii G. Skvortsov, Dmitry M. Lyubov, Anton V. Cherkasov, Georgy K. Fukin, Andrei S. Shavyrin, Dongmei Cui, Alexander A. Trifonov, “Dialkyl Rare Earth Complexes Supported by Potentially Tridentate Amidinate Ligands: Synthesis, Structures, and Catalytic Activity in Isoprene Polymerization”, Eur. J. Inorg. Chem, 2012:13 (2012), 2289  crossref  isi  scopus
    17. Ivan V. Basalov, Dmitry M. Lyubov, Georgy K. Fukin, Andrei S. Shavyrin, Alexander A. Trifonov, “A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers”, Angew. Chem, 2012, n/a  crossref
    18. Ivan V. Basalov, Dmitry M. Lyubov, Georgy K. Fukin, Andrei S. Shavyrin, Alexander A. Trifonov, “A Double Addition of LnH to a Carbon-Carbon Triple Bond and Competitive Oxidation of Ytterbium(II) and Hydrido Centers”, Angew. Chem. Int. Ed, 2012, n/a  crossref  isi  scopus
    19. Karpov A.V., Shavyrin A.S., Cherkasov A.V., Fukin G.K., Trifonov A.A., “Reactions of Bis(Alkyl)Yttrium Complexes Supported by Bulky N,N Ligands with 2,6-Diisopropylaniline and Phenylacetylene”, Organometallics, 31:15 (2012), 5349–5357  crossref  isi  elib  scopus
    20. Tolpygin A.O., Shavyrin A.S., Cherkasov A.V., Fukin G.K., Trifonov A.A., “Chloro and Alkyl Rare-Earth Complexes Supported by Ansa-Bis(Amidinate) Ligands with a Rigid O-Phenylene Linker. Ligand Steric Bulk: a Means of Stabilization Or Destabilization?”, Organometallics, 31:15 (2012), 5405–5413  crossref  isi  elib  scopus
    21. Ivan V. Basalov, Dmitry M. Lyubov, Georgy K. Fukin, Anton V. Cherkasov, Alexander A. Trifonov, “Reactivity of Ytterbium(II) Hydride. Redox Reactions: Ytterbium(II) vs Hydrido Ligand. Metathesis of the Yb–H Bond”, Organometallics, 2013, 1302141447  crossref  isi  scopus
    22. Vasily Rad’kov, Vincent Dorcet, Jean-François Carpentier, Alexander Trifonov, Evgeny Kirillov, “Alkylyttrium Complexes of Amidine–Amidopyridinate Ligands. Intramolecular C(sp3)–H Activation and Reactivity Studies”, Organometallics, 2013, 1302191400  crossref  isi  scopus
    23. A.A.. Kissel, D.M.. Lyubov, T.V.. Mahrova, G.K.. Fukin, A.V.. Cherkasov, “Rare-earth dichloro and bis(alkyl) complexes supported by bulky amido–imino ligand. Synthesis, structure, reactivity and catalytic activity in isoprene polymerization”, Dalton Trans, 42:25 (2013), 9211  crossref  isi  elib  scopus
    24. A.A.. Karpov, A.V.. Cherkasov, G.K.. Fukin, A.S.. Shavyrin, Lapo Luconi, “Yttrium Complexes Featuring Different Y–C Bonds. Comparative Reactivity Studies: Toward Terminal Imido Complexes”, Organometallics, 2013, 1304050956  crossref  isi  scopus
    25. Xiufang Wang, Weijie Peng, Peng Cui, Xuebing Leng, Wei Xia, “Synthesis and Catalytic Activity of Amido-Boratabenzene Complexes of Rare-Earth Metals and Zirconium and Chromium”, Organometallics, 2013, 1310071421  crossref  isi  scopus
    26. A.O.. Tolpygin, G.G.. Skvortsov, A.V.. Cherkasov, G.K.. Fukin, T.A.. Glukhova, “Lanthanide Borohydrido Complexes Supported byansa-Bis(amidinato) Ligands with a Rigido-Phenylene Linker: Effect of Ligand Tailoring on Catalytic Lactide Polymerization”, Eur. J. Inorg. Chem, 2013, n/a  crossref  isi  scopus
    27. A.O.. Tolpygin, A.V.. Cherkasov, G.K.. Fukin, A.A.. Trifonov, “Reversible Switching of Coordination Mode of ansa bis(Amidinate) Ligand in Ytterbium Complexes Driven by Oxidation State of the Metal Atom”, Inorg. Chem, 2014, 1401211114  crossref  isi  scopus
    28. D.M.. Lyubov, Lapo Luconi, Andrea Rossin, Giulia Tuci, A.V.. Cherkasov, “Metal-to-Ligand Alkyl Migration Inducing Carbon-Sulfur Bond Cleavage in Dialkyl Yttrium Complexes Supported by Thiazole-Containing Amidopyridinate Ligands: Synthesis, Characterization, and Catalytic Activity in the Intramolecular Hydroamination Reaction”, Chem. Eur. J, 2014, n/a  crossref  isi  scopus
    29. D.M.. Lyubov, A.V.. Cherkasov, G.K.. Fukin, S.Y.u. Ketkov, A.S.. Shavyrin, “Trinuclear alkyl hydrido rare-earth complexes supported by amidopyridinato ligands: synthesis, structures, C–Si bond activation and catalytic activity in ethylene polymerization”, Dalton Trans, 43:38 (2014), 14450  crossref  isi  elib  scopus
    30. M.M.. Stalzer, Massimiliano Delferro, T.J.. Marks, “Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins”, Catal Lett, 2014  crossref  isi
    31. Lapo Luconi, D.M.. Lyubov, Andrea Rossin, T.A.. Glukhova, A.V.. Cherkasov, “Organolanthanide Complexes Supported by Thiazole-Containing Amidopyridinate Ligands: Synthesis, Characterization, and Catalytic Activity in Isoprene Polymerization”, Organometallics, 2014, 1412080625  crossref  isi  scopus
    32. M.V.. Yakovenko, N.Y.u. Udilova, T.A.. Glukhova, A.V.. Cherkasov, G.K.. Fukin, “Amido rare-earth complexes supported by an ansa bis(amidinate) ligand with a rigid 1,8-naphthalene linker: synthesis, structures and catalytic activity in rac-lactide polymerization and hydrophosphonylation of carbonyl compounds”, New J. Chem, 39:2 (2015), 1083  crossref  isi  elib  scopus
    33. A.A.. Kissel, T.V.. Mahrova, D.M.. Lyubov, A.V.. Cherkasov, G.K.. Fukin, “Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination”, Dalton Trans, 44:27 (2015), 12137  crossref  isi  elib  scopus
    34. A.A.. Trifonov, Boris Shestakov, Jérôme Long, Konstantin Lyssenko, Yannick Guari, “An Organoytterbium(III) Complex Exhibiting Field-Induced Single-Ion-Magnet Behavior”, Inorg. Chem, 2015, 1507281555  crossref  isi  scopus
    35. Tolpygin A.O., Glukhova T.A., Cherkasov A.V., Fukin G.K., Aleksanyan D.V., Cui D., Trifonov A.A., “Bis(Alkyl) Rare-Earth Complexes Supported By a New Tridentate Amidinate Ligand With a Pendant Diphenylphosphine Oxide Group. Synthesis, Structures and Catalytic Activity in Isoprene Polymerization”, Dalton Trans., 44:37 (2015), 16465–16474  crossref  isi  elib  scopus
    36. Skvortsov G.G., Cherkasov A.V., Fukin G.K., Trifonov A.A., “Bisborohydride yttrium complexes containing amidinate ligands [o-Me2NC6H4CH2C(NR)2]Y(BH4)2L n (R = Pri, L = DME, n = 1; R = Cy, L = THF, n = 2). Synthesis, structure, and catalytic activity in polymerization of rac-lactide and isoprene”, Russ. Chem. Bull., 64:12 (2015), 2872–2878  crossref  isi  scopus
    37. Lyubov D.M., Cherkasov A.V., Fukin G.K., Trifonov A.A., “Selective Intermolecular C-H Bond Activation: a Straightforward Synthetic Approach To Heteroalkyl Yttrium Complexes Containing a Bis(Pyrazolyl)Methyl Ligand”, Organometallics, 35:2 (2016), 126–137  crossref  isi  scopus
    38. Rad'kova N.Yu., Tolpygin A.O., Rad'kov V.Yu., Khamaletdinova N.M., Cherkasov A.V., Fukin G.K., Trifonov A.A., “Bis(alkyl) rare-earth complexes coordinated by bulky tridentate amidinate ligands bearing pendant Ph _{2} PO and Ph _{2} PNR groups. Synthesis, structures and catalytic activity in stereospecific isoprene polymerization”, Dalton Trans., 45:46 (2016), 18572–18584  crossref  isi  scopus
    39. Kelly R.P., Roesky P.W., “Catalytic Sigma-Bond Metathesis and the Polymerization of 1,3-Dienes by Rare-Earth Metal Complexes”, 50 Years of Structure and Bonding – The Anniversary Volume, Structure and Bonding, 172, ed. Mingos D., Springer, 2016, 85–117  crossref  isi  scopus
    40. Lyubov D.M., Rad'kov V.Yu., Cherkasov A.V., Fukin G.K., Trifonov A.A., “Scandium, Yttrium, and Ytterbium Bisalkyl Complexes Stabilized By Monoanionic Amidopyridinate Ligands”, Russ. Chem. Bull., 65:11 (2016), 2594–2600  crossref  isi  scopus
    41. Trifonov A.A., Lyubov D.M., “A quarter-century long story of bis(alkyl) rare-earth (III) complexes”, Coord. Chem. Rev., 340 (2017), 10–61  crossref  isi  scopus
    42. Selikhov A.N., Mahrova T.V., Cherkasov A.V., Fukin G.K., Maron L., Trifonov A.A., “Half-Sandwich Alkyl, Amido, and Iodo Samarium(II) Complexes: Non-Conventional Sterically Governed Oxidation of ( t Bu _{4} Carb) _{2} Sm”, Chem.-Eur. J., 23:6 (2017), 1436–1443  crossref  isi  scopus
    43. Skvortsov G.G., Cherkasov A.V., Trifonov A.A., “Triketiminate Bis(Borohydride) Complexes of Rare-Earth Metals [(2,6-Me2C6H3N=Cme)(2)C(2,6-Me2C6H3N=Cbut)]Ln(Bh4)(2)(Thf)(2) (Ln = Y, Nd): Synthesis, Structure, and Catalytic Activity in Polymerization of Rac-Lactide, Epsilon-Caprolactone, and Isoprene”, Russ. Chem. Bull., 66:9 (2017), 1665–1674  crossref  isi  scopus
    44. Lyubov D.M., Cherkasov A.V., Fukin G.K., Lyssenko K.A., Rychagova E.A., Ketkov S.Yu., Trifonov A.A., “Rare-Earth Metal-Mediated Phcu N Insertion Into N, N-Bis( Trimethylsilyl) Naphthalene-1,8-Diamido Dianion - a Synthetic Approach to Complexes Coordinated By Ansa-Bridged Amido-Amidinato Ligand”, Dalton Trans., 47:2 (2018), 438–451  crossref  isi  scopus
    45. Liu J., Chen W., Li J., Cui Ch., “Rare-Earth-Catalyzed Regioselective Hydrosilylation of Aryl-Substituted Internal Alkenes”, ACS Catal., 8:3 (2018), 2230–2235  crossref  isi  scopus
    46. Ma Y.-Zh., Pushkarevsky N.A., Sukhikh T.S., Galashov A.E., Makarov A.G., Roesky P.W., Konchenko S.N., “Steric Influence and Intermolecular Interactions of Formamidinate Ligands in Lanthanide (Sm, Yb) Arylchalcogenolate Complexes”, Eur. J. Inorg. Chem., 2018, no. 29, 3388–3396  crossref  isi  scopus
    47. Abakumov G.A. Piskunov A.V. Cherkasov V.K. Fedushkin I.L. Ananikov V.P. Eremin D.B. Gordeev E.G. Beletskaya I.P. Averin A.D. Bochkarev M.N. Trifonov A.A. Dzhemilev U.M. D'yakonov V.A. Egorov M.P. Vereshchagin A.N. Syroeshkin M.A. Jouikov V.V. Muzafarov A.M. Anisimov A.A. Arzumanyan A.V. Kononevich Yu.N. Temnikov M.N. Sinyashin O.G. Budnikova Yu.H. Burilov A.R. Karasik A.A. Mironov V.F. Storozhenko P.A. Shcherbakova G.I. Trofimov B.A. Amosova S.V. Gusarova N.K. Potapov V.A. Shur V.B. Burlakov V.V. Bogdanov V.S. Andreev M.V., “Organoelement Chemistry: Promising Growth Areas and Challenges”, Russ. Chem. Rev., 87:5 (2018), 393–507  mathnet  crossref  isi  scopus
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    49. Tolpygin A.O., Linnikova O.A., Kovylina T.A., Cherkasov V A., Fukin G.K., Trifonov A.A., “Neodymium Dihalide Complexes With a Tridentate Amidinate Phosphine Oxide Ligand: Synthesis, Structure, and Catalytic Activity in Isoprene Polymerization”, Russ. Chem. Bull., 68:1 (2019), 32–39  crossref  isi  scopus
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