RUS  ENG JOURNALS   PEOPLE   ORGANISATIONS   CONFERENCES   SEMINARS   VIDEO LIBRARY   PERSONAL OFFICE
General information
Latest issue
Archive
Impact factor
Guidelines for authors

Search papers
Search references

RSS
Latest issue
Current issues
Archive issues
What is RSS



Usp. Khim.:
Year:
Volume:
Issue:
Page:
Find






Personal entry:
Login:
Password:
Save password
Enter
Forgotten password?
Register


Usp. Khim., 1981, Volume 50, Issue 5, Pages 860–888 (Mi rcr3309)  

The Structure and the Electron-donating Properties of Tertiary Arsine Oxides

B. N. Laskorin, V. V. Yakshin, N. A. Lyubosvetova


Abstract: The complex-forming and physicochemical properties of tertiary arsine oxides are analysed in connection with the significant differences between them and the closest organophosphorus analogues. Attention is focused on the reactivities of organoarsenic ligands in complex-formation reactions with acids and metal salts. The specific features of the steric and electronic structures of arsine oxides and the mechanism of the transmission of the influences from groups via the arsenic atom to the reaction centre (the arsenyl oxygen) are discussed. Heterophase reactions in the extraction of acids and salts are considered within the framework of a single model of donor–acceptor processes in solution.
The bibliography includes 274 references.

Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=2627

English version:
Russian Chemical Reviews, 1981, 50:5, 454–469

Bibliographic databases:

Document Type: Article
UDC: 541.49+542.61+547.242.04

Citation: B. N. Laskorin, V. V. Yakshin, N. A. Lyubosvetova, “The Structure and the Electron-donating Properties of Tertiary Arsine Oxides”, Usp. Khim., 50:5 (1981), 860–888; Russian Chem. Reviews, 50:5 (1981), 454–469

Linking options:
  • http://mi.mathnet.ru/eng/rcr3309
  • http://mi.mathnet.ru/eng/rcr/v50/i5/p860

    SHARE: VKontakte.ru FaceBook Twitter Mail.ru Livejournal Memori.ru


    Citing articles on Google Scholar: Russian citations, English citations
    Related articles on Google Scholar: Russian articles, English articles
  • Успехи химии Russian Chemical Reviews
    Number of views:
    This page:64

     
    Contact us:
     Terms of Use  Registration  Logotypes © Steklov Mathematical Institute RAS, 2019