The Chemistry of Stabilised Sulphonium Ylides
Yu. V. Belkin, N. A. Polezhaeva
Kazan State University A. Butlerov Institute of Chemistry
The review is devoted to the chemistry of stabilised sulphonium ylides, i.e. ylides with substituents at the carbanionic carbon atom capable of delocalising its negative charge. The physical properties of compounds of this class are examined and the methods of synthesis of stabilised sulphonium ylides, their rearrangements, and their reactions with electrophiles and nucleophiles are described. The structures and reactivities of the complexes of stabilised sulphonium ylides with transition metals and their organometallic derivatives are considered. The practical applications of the stabilised sulphonium ylides are indicated.
The bibliography includes 272 references.
Russian Chemical Reviews, 1981, 50:5, 481–497
Yu. V. Belkin, N. A. Polezhaeva, “The Chemistry of Stabilised Sulphonium Ylides”, Usp. Khim., 50:5 (1981), 909–942; Russian Chem. Reviews, 50:5 (1981), 481–497
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