Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals
G. A. Razuvaev, L. I. Vyshinskaya
Chemistry Research Institute, State University of Gor'kii
A systematic account is given of the literature data on the methods of synthesis and reactivities of transition metal σ-derivatives RnM and RnMXm–n(X = halogen, OR', acac, or NR'2; R' = Me, Et, or Ph; n = valence of the metal) for transition metals in the Ti, V, and Cr subgroups. The influence of the nature of the central atom and of the character of the σ-substituents on the mode of thermal decomposition is discussed. The mechanisms of reactions involving insertion in the transition metal–carbon σ-bond are considered.
The bibliography includes 124 references.
Russian Chemical Reviews, 1983, 52:10, 944–959
G. A. Razuvaev, L. I. Vyshinskaya, “Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals”, Usp. Khim., 52:10 (1983), 1648–1675; Russian Chem. Reviews, 52:10 (1983), 944–959
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