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Usp. Khim., 1985, Volume 54, Issue 4, Pages 591–618 (Mi rcr3625)  

This article is cited in 2 scientific papers (total in 2 papers)

The Electronic Structure of Transition Metal Cluster Complexes with Weak- and Strong-field Ligands

G. P. Kostikova, D. V. Korol'kov

Leningrad State University

Abstract: A systematic account and a survey of the results of quantum-chemical and spectroscopic studies of the electronic structure of transition metal cluster complexes are presented. In terms of the theory of canonical molecular orbitals and the theory of weak- and strong-field ligands, the concept of the structure and stability of the clusters taking into account the influence of the ligands and transition metal atoms on the characteristics of the M–M bonds has been formulated. The characteristic features of the delocalisation of the valence electrons of the M atoms in the Mn groups, the intercluster interaction, the density of the M atoms in the clusters, and the effects of cluster formation in the optical and X-ray spectra are discussed.
The bibliography includes 137 references.

Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=3040

English version:
Russian Chemical Reviews, 1985, 54:4, 344–360

Bibliographic databases:

Document Type: Article
UDC: 541.57+546.7/8

Citation: G. P. Kostikova, D. V. Korol'kov, “The Electronic Structure of Transition Metal Cluster Complexes with Weak- and Strong-field Ligands”, Usp. Khim., 54:4 (1985), 591–618; Russian Chem. Reviews, 54:4 (1985), 344–360

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    This publication is cited in the following articles:
    1. Tsivadze A.Yu. Ionova G.V. Mikhalko V.K. Kostrubov Yu.N., “Thermodynamics and Mechanisms of Formation of Supramolecules and Supramolecular Assemblies of S-, P-, D- and F-Elements Problems and Prospects”, Uspekhi Khimii, 76:3 (2007), 237–259  mathnet  isi
    2. Kozlova M.N., Enyashin A.N., Fedorov V.E., “Quantum-chemical study of quasi-one-dimensional vanadium and niobium sulfides with Peierls distortion”, J. Struct. Chem., 57:8 (2016), 1505–1512  crossref  isi
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