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Усп. хим., 2005, том 74, выпуск 1, страницы 5–23 (Mi rcr381)  

Эта публикация цитируется в 93 научных статьях (всего в 93 статьях)

Полиэлектролитные комплексы в растворе и в конденсированной фазе

В. А. Кабанов

Московский государственный университет имени М. В. Ломоносова, химический факультет

Аннотация: Рассмотрены термодинамика, кинетика и механизмы реакций между противоположно заряженными полиэлектролитами в водных растворах, приводящих к образованию нерастворимых стехиометричных или растворимых нестехиометричных интерполиэлектролитных комплексов. Обсуждены механизмы реакций полиэлектролитного обмена. Отмечено, что поведение равновесных нестехиометричных интерполиэлектролитных комплексов в водных растворах характеризуется двойственностью: с одной стороны, они проявляют свойства обычных линейных полиэлектролитов, с другой — ведут себя подобно амфифильным блок-сополимерам. При добавлении низкомолекулярных солей в растворы интерполиэлектролитных комплексов обычно происходят перераспределение электростатически связанных цепей и фазовое разделение. Анализ этих процессов имеет ключевое значение для представления таких комплексов как особого семейства полимерных материалов. Приведены некоторые данные о конформациях полиионов в твердых интерполиэлектролитных комплексах и рассмотрены их термомеханические свойства в набухшем состоянии.
Библиография — 117 ссылок.

Полный текст: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=1165

Англоязычная версия:
Russian Chemical Reviews, 2005, 74:1, 3–20

Реферативные базы данных:

Тип публикации: Статья
Поступила в редакцию: 24.08.2004

Образец цитирования: В. А. Кабанов, “Полиэлектролитные комплексы в растворе и в конденсированной фазе”, Усп. хим., 74:1 (2005), 5–23; Russian Chem. Reviews, 74:1 (2005), 3–20

Образцы ссылок на эту страницу:
  • http://mi.mathnet.ru/rcr381
  • http://mi.mathnet.ru/rus/rcr/v74/i1/p5

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    Citing articles on Google Scholar: Russian citations, English citations
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