This article is cited in 2 scientific papers (total in 2 papers)
Arynes, diaryliodonium salts and azine N-oxides in transition metal-free electrophilic N-arylation
D. I. Bugaenko, A. V. Karchava, M. A. Yurovskaya
Lomonosov Moscow State University, Faculty of Chemistry
The main approach to the synthesis of aromatic and heteroaromatic amines is based on palladium- and copper-catalyzed N-arylation reactions. Although these methods are highly efficient and provide extensive opportunities for the synthesis of (het)arylamines with various structures and properties, they have some limitations related to the catalysts used and reaction conditions. This review addresses alternative approaches to N-(het)arylation that have been extensively developed in the past decade and are based on the use of arynes, diaryliodonium salts and azine N-oxides as electrophilic (het)arylating agents. Because of mild reaction conditions and no need for catalysts and strong bases, these N-(het)arylation methods are attractive for various synthetic applications and open up new possibilities for the preparation of valuable organic compounds inaccessible via traditional catalytic methods. The attention is focussed on publications of the last decade.
The bibliography includes 112 references.
Russian Chemical Reviews, 2018, 87:3, 272–301
D. I. Bugaenko, A. V. Karchava, M. A. Yurovskaya, “Arynes, diaryliodonium salts and azine N-oxides in transition metal-free electrophilic N-arylation”, Usp. Khim., 87:3 (2018), 272–301; Russian Chem. Reviews, 87:3 (2018), 272–301
Citation in format AMSBIB
\by D.~I.~Bugaenko, A.~V.~Karchava, M.~A.~Yurovskaya
\paper Arynes, diaryliodonium salts and azine N-oxides in transition metal-free electrophilic N-arylation
\jour Usp. Khim.
\jour Russian Chem. Reviews
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Bugaenko I D., Yurovskaya M.A., Karchava V A., “N-Arylation of Dabco With Diaryliodonium Salts: General Synthesis of N-Aryl-Dabco Salts as Precursors For 1,4-Disubstituted Piperazines”, Org. Lett., 20:20 (2018), 6389–6393
Bugaenko D.I., “New Methodology For One -Pot C H Functionalization of Pyridines Without the Use of Transition Metal Catalysts (Microreview)”, Chem. Heterocycl. Compds., 54:9 (2018), 829–831
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