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Usp. Khim., 2018, Volume 87, Issue 6, Pages 586–603 (Mi rcr4213)  

This article is cited in 1 scientific paper (total in 1 paper)

Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids

T. V. Andrushkevich, Yu. A. Chesalov

Boreskov Institute of Catalysis SB RAS, Novosibirsk

Abstract: The results of studies on the mechanism of heterogeneous catalytic oxidation of organic compounds of different chemical structure to carboxylic acids are analyzed and generalized. The concept developed by Academician G. K. Boreskov, according to which the direction of the reaction is governed by the structure and bond energy of surface intermediates, was confirmed taking the title processes as examples. Quantitative criteria of the bond energies of surface compounds of oxidizable reactants, reaction products and oxygen that determine the selective course of the reaction are presented.
The bibliography includes 195 references.

Funding Agency Grant Number
Russian Academy of Sciences - Federal Agency for Scientific Organizations 0303-2016-0006


Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=4779

English version:
Russian Chemical Reviews, 2018, 87:6, 586–603

Bibliographic databases:

Document Type: Article
Received: 22.08.2017

Citation: T. V. Andrushkevich, Yu. A. Chesalov, “Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids”, Usp. Khim., 87:6 (2018), 586–603; Russian Chem. Reviews, 87:6 (2018), 586–603

Citation in format AMSBIB
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\by T.~V.~Andrushkevich, Yu.~A.~Chesalov
\paper Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids
\jour Usp. Khim.
\yr 2018
\vol 87
\issue 6
\pages 586--603
\mathnet{http://mi.mathnet.ru/rcr4213}
\transl
\jour Russian Chem. Reviews
\yr 2018
\vol 87
\issue 6
\pages 586--603
\crossref{https://doi.org/10.1070/RCR4779}
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\scopus{http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85048052327}


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    This publication is cited in the following articles:
    1. Sprung Ch., Yablonsky G.S., Schloegl R., Trunschke A., “Constructing a Rational Kinetic Model of the Selective Propane Oxidation Over a Mixed Metal Oxide Catalyst”, Catalysts, 8:8 (2018), 330  crossref  isi
  • Успехи химии Russian Chemical Reviews
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