Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids
T. V. Andrushkevich, Yu. A. Chesalov
Boreskov Institute of Catalysis SB RAS, Novosibirsk
The results of studies on the mechanism of heterogeneous catalytic oxidation of organic compounds of different chemical structure to carboxylic acids are analyzed and generalized. The concept developed by Academician G. K. Boreskov, according to which the direction of the reaction is governed by the structure and bond energy of surface intermediates, was confirmed taking the title processes as examples. Quantitative criteria of the bond energies of surface compounds of oxidizable reactants, reaction products and oxygen that determine the selective course of the reaction are presented.
The bibliography includes 195 references.
Russian Chemical Reviews, 2018, 87:6, 586–603
T. V. Andrushkevich, Yu. A. Chesalov, “Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids”, Usp. Khim., 87:6 (2018), 586–603; Russian Chem. Reviews, 87:6 (2018), 586–603
Citation in format AMSBIB
\by T.~V.~Andrushkevich, Yu.~A.~Chesalov
\paper Mechanism of heterogeneous catalytic oxidation of organic compounds to carboxylic acids
\jour Usp. Khim.
\jour Russian Chem. Reviews
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