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Usp. Khim., 2018, Volume 87, Issue 7, Pages 707–725 (Mi rcr4218)  

Molecular design of stable diarylnitroxides

T. V. Magdesieva, O. A. Levitskiy

Lomonosov Moscow State University, Faculty of Chemistry

Abstract: The review is devoted to diarylnitroxides, which constitute an important type of organic radicals. These compounds are much less investigated than their alkyl counterparts. Meanwhile, they are of great interest, since they provide extensive opportunities for targeted structural modification and control of electronic properties of a molecule for a particular practical application. The existing trends of molecular design of stable diarylnitroxides and general approaches to their synthesis are discussed. Structural details and spin density distribution in diarylnitroxides are considered. Factors determining the stability of both the diarylnitroxide radicals and their oxidized and reduced forms and the redox properties of this class of organic radicals are addressed.
The bibliography includes 128 references.

Funding Agency Grant Number
Russian Science Foundation 16-13-10282


Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=4769

English version:
Russian Chemical Reviews, 2018, 87:7, 707–725

Document Type: Article
Received: 27.07.2017

Citation: T. V. Magdesieva, O. A. Levitskiy, “Molecular design of stable diarylnitroxides”, Usp. Khim., 87:7 (2018), 707–725; Russian Chem. Reviews, 87:7 (2018), 707–725

Citation in format AMSBIB
\Bibitem{MagLev18}
\by T.~V.~Magdesieva, O.~A.~Levitskiy
\paper Molecular design of stable diarylnitroxides
\jour Usp. Khim.
\yr 2018
\vol 87
\issue 7
\pages 707--725
\mathnet{http://mi.mathnet.ru/rcr4218}
\transl
\jour Russian Chem. Reviews
\yr 2018
\vol 87
\issue 7
\pages 707--725
\crossref{https://doi.org/10.1070/RCR4769}


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