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Usp. Khim., 2018, Volume 87, Issue 8, Pages 797–820 (Mi rcr4222)  

Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes

V. A. D'yakonov, G. N. Kadikova, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis of RAS, Ufa

Abstract: The current review summarizes the published data on transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes. It addresses homodimerization of cycloheptatrienes and cyclocodimerization of the latter with alkenes, dienes and alkynes in the presence of transition metal complexes that occur via [2$\pi$+2$\pi$], [3$\pi$+2$\pi$], [6$\pi$+2$\pi$], [6$\pi$+4$\pi$] and [6$\pi$+2$\pi$+2$\pi$] cycloadditions. Special attention is given to the application of these reactions in the synthesis of valuable strained bi-, tri- and polycyclic compounds and for the development of methods of stereoselective synthesis of natural products.
The bibliography includes 91 references.

Funding Agency Grant Number
Russian Science Foundation 17-73-10096


Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=4793

English version:
Russian Chemical Reviews, 2018, 87:8, 797–820

Document Type: Article
Received: 26.10.2017

Citation: V. A. D'yakonov, G. N. Kadikova, U. M. Dzhemilev, “Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes”, Usp. Khim., 87:8 (2018), 797–820; Russian Chem. Reviews, 87:8 (2018), 797–820

Citation in format AMSBIB
\Bibitem{DyaKadDzh18}
\by V.~A.~D'yakonov, G.~N.~Kadikova, U.~M.~Dzhemilev
\paper Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes
\jour Usp. Khim.
\yr 2018
\vol 87
\issue 8
\pages 797--820
\mathnet{http://mi.mathnet.ru/rcr4222}
\transl
\jour Russian Chem. Reviews
\yr 2018
\vol 87
\issue 8
\pages 797--820
\crossref{https://doi.org/10.1070/RCR4793}


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