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Usp. Khim., 2018, Volume 87, Issue 11, Pages 1139–1167 (Mi rcr4229)  

Scandium-organic frameworks: progress and prospects

M. O. Barsukovaab, S. A. Sapchenkoabc, D. N. Dybtsevab, V. P. Fedinab

a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk
b Novosibirsk State University
c School of Chemistry, University of Manchester, UK

Abstract: Metal-organic frameworks (MOFs) represent a class of crystalline coordination compounds with periodic structures composed of metal cations or clusters connected by organic linkers. In recent years, increasing interest has been attracted to the synthesis and study of MOFs based on oxophilic cations of early transition metals, first of all, $\mathrm{Zr}^{\mathrm{IV}}$, $\mathrm{Hf}^{\mathrm{IV}}$, $\mathrm{Ti}^{\mathrm{IV}}$, $\mathrm{Sc}^{\mathrm{III}}$, and also main group $\mathrm{Al}^{\mathrm{III}}$ cations. The carboxylate complexes of these metals possess high stability, which ensures the chemical robustness of the corresponding coordination polymers. The MOFs based on scandium(III) and oxygen-containing ligands are promising for the design of porous materials possessing high specific surface areas, high hydrolytic and thermal stabilities of the coordination framework and diverse functional properties. This review addresses the chemistry of metal-organic frameworks based on scandium(III). Published data on the synthesis and crystal structure characterization of scandium-containing coordination polymers available before 2018 are discussed. The properties of these compounds are considered.
The bibliography includes 101 references.

Funding Agency Grant Number
Russian Science Foundation 17-73-10254


Full text: http://www.uspkhim.ru/.../paper_rus.phtml?journal_id=rc&paper_id=4826

English version:
Russian Chemical Reviews, 2018, 87:11, 1139–1167

Bibliographic databases:

Document Type: Article
Received: 06.04.2018

Citation: M. O. Barsukova, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin, “Scandium-organic frameworks: progress and prospects”, Usp. Khim., 87:11 (2018), 1139–1167; Russian Chem. Reviews, 87:11 (2018), 1139–1167

Citation in format AMSBIB
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\by M.~O.~Barsukova, S.~A.~Sapchenko, D.~N.~Dybtsev, V.~P.~Fedin
\paper Scandium-organic frameworks: progress and prospects
\jour Usp. Khim.
\yr 2018
\vol 87
\issue 11
\pages 1139--1167
\mathnet{http://mi.mathnet.ru/rcr4229}
\transl
\jour Russian Chem. Reviews
\yr 2018
\vol 87
\issue 11
\pages 1139--1167
\crossref{https://doi.org/10.1070/RCR4826}
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\scopus{http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85056103395}


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