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TVT, 2006, Volume 44, Issue 1, Pages 50–58 (Mi tvt1288)  

Thermophysical Properties of Materials

The pressure–temperature–concentration correlation for aqueous solutions of hydroperoxide

N. M. Kuznetsov, S. M. Frolov

N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow

Abstract: The results of analysis of available experimental data on the pressure dependence of temperature of nonequilibrium boiling of rapidly heated aqueous solutions of hydroperoxide are used to determine the pressure$(P)$–temperature $(T)$–concentration$(x)$ correlation. This correlation is obtained for a solution under conditions of phase equilibrium (saturation surface in three-dimensional space of variables $P$, $T$, and $x$) in a wide range of states, including the critical line. The obtained surface is used to calculate the equilibrium composition of gas over the solution as a function of $x$ and $T$ by solving the Duhem equation.

Full text: PDF file (1719 kB)

English version:
High Temperature, 2006, 44:1, 47–56

UDC: 536.423
Received: 16.11.2004

Citation: N. M. Kuznetsov, S. M. Frolov, “The pressure–temperature–concentration correlation for aqueous solutions of hydroperoxide”, TVT, 44:1 (2006), 50–58; High Temperature, 44:1 (2006), 47–56

Citation in format AMSBIB
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\by N.~M.~Kuznetsov, S.~M.~Frolov
\paper The pressure--temperature--concentration correlation for aqueous solutions of hydroperoxide
\jour TVT
\yr 2006
\vol 44
\issue 1
\pages 50--58
\mathnet{http://mi.mathnet.ru/tvt1288}
\elib{http://elibrary.ru/item.asp?id=9242445}
\transl
\jour High Temperature
\yr 2006
\vol 44
\issue 1
\pages 47--56
\crossref{https://doi.org/10.1007/s10740-006-0006-2}
\elib{http://elibrary.ru/item.asp?id=13507670}
\scopus{http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-33644926689}


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