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TVT, 1991, Volume 29, Issue 2, Pages 281–285 (Mi tvt3930)  

Thermophysical Properties of Materials

Thermodynamic properties of borides of transition metals

A. V. Blinder, A. S. Bolgar

Institute of Materials Science Problems, Academy of Sciences of UkSSR

Abstract: This article generalizes and analyzes results of systematic experimental studies of the heat capacity and enthalpy of borides of metals of groups $ IV$–$\rm VI$ of the periodic system. The laws governing the change in these characteristics are established in relation to the position of the boride-forming metal in the periodic system and the boron content for compounds of a given metal. An empirical equation is obtained and used as a basis for calculation of the temperature dependence of enthalpy in the temperature range $400$$2200$ K for $19$ experimentally studied borides of transition metals. Possible components of the high-temperature heat capacity of the borides are analyzed. The coefficients of isothermal compressibility of the experimentally studied borides are evaluated.

Full text: PDF file (858 kB)

English version:
High Temperature, 1991, 29:2, 214–217

Bibliographic databases:
UDC: 538.722+546.271
Received: 08.08.1989

Citation: A. V. Blinder, A. S. Bolgar, “Thermodynamic properties of borides of transition metals”, TVT, 29:2 (1991), 281–285; High Temperature, 29:2 (1991), 214–217

Citation in format AMSBIB
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\by A.~V.~Blinder, A.~S.~Bolgar
\paper Thermodynamic properties of borides of transition metals
\jour TVT
\yr 1991
\vol 29
\issue 2
\pages 281--285
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\transl
\jour High Temperature
\yr 1991
\vol 29
\issue 2
\pages 214--217
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