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TVT, 2013, Volume 51, Issue 1, Pages 41–46 (Mi tvt53)  

Plasma Investigations

The effective mass of charged clusters in weakly conducting liquids

V. A. Dashkovskiia, I. Chikinab

a Institute for Solid State Physics, Russian Academy of Sciences, Chernogolovka, Russia
b IRAMIS, LIONS, UMR SIS2M 3299 CEA-CNRS, CEA-Saclay, F-91191 Gif-sur-Yvette Cedex, France

Abstract: The existing possibilities to determine the mass of charged clusters $M_i$ in weak liquid electrolytes are discussed. It was noted that the standard relaxation influence of the finite values of $M_i$ on the frequency dependence of the three-dimensional conductivity $\sigma_3(\omega)$ of a weak electrolyte becomes observable in the range of sufficiently high frequencies where other types of absorption such as Debye relaxation (which occurs when $\omega\approx\omega_D$) are also activated. This work presents a methodology that allows taking data related to $M_i$ in the low-frequency domain $\omega\ll\omega_D$ using a special differential procedure. Planar $\sigma_{\parallel}(\omega)$ and vertical $\sigma_{\perp}(\omega)$ low-frequency conductivities in two-dimensional ionic system in the presence of vertical electric field $E_\perp$ are measured with further definition of their difference $\delta\sigma=\sigma_\parallel(\omega)-\sigma_\perp(\omega)$, which contains the information on $M_i$.

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English version:
High Temperature, 2013, 51:1, 34–39

Bibliographic databases:

UDC: 532.6;533.9
Received: 16.02.2012

Citation: V. A. Dashkovskii, I. Chikina, “The effective mass of charged clusters in weakly conducting liquids”, TVT, 51:1 (2013), 41–46; High Temperature, 51:1 (2013), 34–39

Citation in format AMSBIB
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