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TVT, 2011, Volume 49, Issue 6, Pages 862–871 (Mi tvt594)  

This article is cited in 11 scientific papers (total in 11 papers)

Thermophysical Properties of Materials

Equation of State and Thermodynamic Properties of Saturated and Superheated Mercury Vapors up to $1650$ K and $125$ MPa

L. R. Fokina, V. N. Popova, S. P. Naurzakovb

a Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow
b Russian Research Centre "Kurchatov Institute", Moscow

Abstract: Experimental data on the compressibility, sound velocity, and saturation pressures have been generalized for mercury vapor at densities $<3$ g/cm$^2$ based on the equation of state with the second, third, and fourth virial coefficients. The virial coefficients have been calculated using the three-parameter Lennard-Jones potential $m$–6. The data have been generalized using the nonlinear weighted least-squares method. The parameters of the models and their enlarged error matrix taking into account random and systematic (in the first approximation) errors of the experimental data have been determined. Tables of thermodynamic properties of the saturated and superheated vapor have been calculated. The enthalpy drop error has been correctly calculated on the isentropic curve of the superheated vapor taking into account covariations of the equation of state parameters.

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English version:
High Temperature, 2011, 49:6, 832–840

Bibliographic databases:

UDC: 536.7
Received: 02.12.2010

Citation: L. R. Fokin, V. N. Popov, S. P. Naurzakov, “Equation of State and Thermodynamic Properties of Saturated and Superheated Mercury Vapors up to $1650$ K and $125$ MPa”, TVT, 49:6 (2011), 862–871; High Temperature, 49:6 (2011), 832–840

Citation in format AMSBIB
\by L.~R.~Fokin, V.~N.~Popov, S.~P.~Naurzakov
\paper Equation of State and Thermodynamic Properties of Saturated and Superheated Mercury Vapors up to $1650$~K and $125$~MPa
\jour TVT
\yr 2011
\vol 49
\issue 6
\pages 862--871
\jour High Temperature
\yr 2011
\vol 49
\issue 6
\pages 832--840

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    This publication is cited in the following articles:
    1. V. N. Popov, “Thermal properties of mercury on the basis of model potentials”, High Temperature, 50:6 (2012), 700–707  mathnet  crossref  isi  elib  elib
    2. D. K. Belashchenko, “Application of the embedded atom model to liquid mercury”, High Temperature, 51:1 (2013), 40–48  mathnet  crossref  isi  elib  elib
    3. E. E. Son, “Current investigations of thermophysical properties of substances (based on recent publications in the journal High Temperature)”, High Temperature, 51:3 (2013), 351–368  mathnet  crossref  isi  elib  elib
    4. L. R. Fokin, V. N. Popov, “General function of the unit compressibility factor for liquid and gaseous mercury”, High Temperature, 51:4 (2013), 465–468  mathnet  crossref  crossref  isi  elib  elib
    5. Wiebke J., Wormit M., Hellmann R., Pahl E., Schwerdtfeger P., “Can an Ab Initio Three-Body Virial Equation Describe the Mercury Gas Phase?”, J. Phys. Chem. B, 118:12 (2014), 3392–3400  crossref  isi  elib
    6. L. R. Fokin, “Reliability of data on the thermophysical properties of materials: Three examples”, High Temperature, 53:2 (2015), 206–213  mathnet  crossref  crossref  isi  elib  elib
    7. Zhukhovitskii D.I., “the Cluster Model of a Hot Dense Vapor”, J. Chem. Phys., 142:16 (2015), 164704  crossref  isi  elib
    8. V. S. Vorob'ev, E. M. Apfel'baum, “The generalized scaling laws based on several deductions from the van der Waals equation”, High Temperature, 54:2 (2016), 175–185  mathnet  crossref  crossref  isi  elib
    9. I. Polishuk, F. Nakonechny, N. Brauner, “Predicting phase behavior of metallic mercury in liquid and compressed gaseous hydrocarbons”, Fuel, 174 (2016), 197–205  crossref  isi
    10. Belashchenko D.K., “Molecular Dynamics Simulation of the Thermodynamic Properties of Mercury At Pressures Below 2.5 Gpa and Temperatures Below 10000 K”, Russ. J. Phys. Chem. A, 91:8 (2017), 1392–1400  crossref  isi  scopus
    11. Leonov V.N., Rodina E.A., Chernetsov N.G., Chernobrovkin Yu.V., Shevchenko A.B., “Passive Negative-Reactivity Injector For a Lead-Cooled Fast Reactor”, Atom. Energy, 122:1 (2017), 9–14  crossref  isi  scopus
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