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TVT, 2013, Volume 51, Issue 1, Pages 86–96 (Mi tvt60)  

This article is cited in 3 scientific papers (total in 3 papers)

Heat and Mass Transfer and Physical Gasdynamics

Fluctuation statistical theory of nucleation in water vapors at near-critical temperatures

S. V. Shevkunov

St. Petersburg State Polytechnical University, St. Petersburg, 195251, Russia

Abstract: The Monte Carlo method has been used to study the evolution of the statistical behavior of density fluctuations in water vapors when approaching the critical isotherm from low temperatures. The free energy, work, and entropy of the formation of the nanosize density fluctuations have been calculated numerically. The spontaneous formation of the critical nucleus of the condensed phase is possible only against the back-ground of the density fluctuations with dimensions exceeding a certain threshold value $n^*$, which increases rapidly when the critical temperature is approached. One should expect a qualitative change in the mechanism of the growth of nuclei of the condensed phase in the region of near critical temperatures from the statistically independent acts of the absorption of monomers by the surface of a microdroplet to the strongly correlated density fluctuations of expanding spatial dimensions.

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English version:
High Temperature, 2013, 51:1, 79–89

Bibliographic databases:

UDC: 536.77, 536.752
Received: 27.10.2011

Citation: S. V. Shevkunov, “Fluctuation statistical theory of nucleation in water vapors at near-critical temperatures”, TVT, 51:1 (2013), 86–96; High Temperature, 51:1 (2013), 79–89

Citation in format AMSBIB
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\by S.~V.~Shevkunov
\paper Fluctuation statistical theory of nucleation in water vapors at near-critical temperatures
\jour TVT
\yr 2013
\vol 51
\issue 1
\pages 86--96
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\transl
\jour High Temperature
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\vol 51
\issue 1
\pages 79--89
\crossref{https://doi.org/10.1134/S0018151X12060090}
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    Citing articles on Google Scholar: Russian citations, English citations
    Related articles on Google Scholar: Russian articles, English articles

    This publication is cited in the following articles:
    1. S. V. Shevkunov, “Structure and stability of hydrogen bonds under conditions of heating in nanopores”, High Temperature, 53:2 (2015), 259–271  mathnet  crossref  crossref  isi  elib  elib
    2. A. Yu. Varaksin, “Effect of particles on carrier gas flow turbulence”, High Temperature, 53:3 (2015), 423–444  mathnet  crossref  crossref  isi  elib  elib
    3. S. V. Shevkunov, “Spin states of electrons in quantum dots upon heating. Simulation by the Feynman path integral method. Magnetic properties”, High Temperature, 55:1 (2017), 12–19  mathnet  crossref  crossref  isi  elib  elib
  • Teplofizika vysokikh temperatur Teplofizika vysokikh temperatur
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