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TVT, 2014, Volume 52, Issue 4, Pages 543–555 (Mi tvt619)  

This article is cited in 3 scientific papers (total in 3 papers)

Thermophysical Properties of Materials

The Rate Constant of Diatomic Molecule Dissociation within the Shock Forced Oscillator Model (SFO Model)

D. L. Tsyganov

Instituto de Plasmas e Fusão Nuclear

Abstract: A numerical analytical investigation of the shock forced oscillator (SFO) model as applied to the "diatomic molecule $AB$–structureless particle $M$" system is continued. The SFO model is based on the quantum theory of strong perturbations and allows one to estimate probabilities $W_{i \to f}$ for the transitions from level $i$ to level $f$ of diatomic molecule $AB$. The numerical analysis was carried out by the example of the nitrogen molecule $N_2$, with anharmonic description of the internuclear interaction potential. The intermolecular interaction potentials in the $N_2$–$N_2$ system are numerically analyzed using the Morse potential, the classical Lennard-Jones potential, and the "improved" Lennard-Jones potential.

DOI: https://doi.org/10.7868/S0040364414030272

Full text: PDF file (503 kB)
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English version:
High Temperature, 2014, 52:4, 518–529

Bibliographic databases:

UDC: 544.42,544.08
Received: 24.04.2013

Citation: D. L. Tsyganov, “The Rate Constant of Diatomic Molecule Dissociation within the Shock Forced Oscillator Model (SFO Model)”, TVT, 52:4 (2014), 543–555; High Temperature, 52:4 (2014), 518–529

Citation in format AMSBIB
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\by D.~L.~Tsyganov
\paper The Rate Constant of Diatomic Molecule Dissociation within the Shock Forced Oscillator Model (SFO Model)
\jour TVT
\yr 2014
\vol 52
\issue 4
\pages 543--555
\mathnet{http://mi.mathnet.ru/tvt619}
\crossref{https://doi.org/10.7868/S0040364414030272}
\elib{http://elibrary.ru/item.asp?id=21803756}
\transl
\jour High Temperature
\yr 2014
\vol 52
\issue 4
\pages 518--529
\crossref{https://doi.org/10.1134/S0018151X14030274}
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    Citing articles on Google Scholar: Russian citations, English citations
    Related articles on Google Scholar: Russian articles, English articles

    This publication is cited in the following articles:
    1. D. L. Tsyganov, “Rate constant of $VT/VV$ energy exchange in the collision di- or polyatomic molecules within the SFO model”, High Temperature, 54:1 (2016), 67–76  mathnet  crossref  crossref  isi  elib
    2. D. L. Tsyganov, “Inelastic collisions of molecules within the SFO model”, High Temperature, 55:1 (2017), 63–69  mathnet  crossref  crossref  isi  elib
    3. D. L. Tsyganov, “Calculating constants of the rates of the reactions of excitation, ionization, and atomic exchange: a model of a shock oscillator with a change of the Hamiltonian of the system”, Russ. J. Phys. Chem. A, 91:11 (2017), 2161–2169  crossref  isi  scopus
  • Teplofizika vysokikh temperatur Teplofizika vysokikh temperatur
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