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 TVT, 2009, Volume 47, Issue 3, Pages 360–370 (Mi tvt815)

Thermophysical Properties of Materials

The absorption of carbon and nitrogen monoxides by ultradisperse aqueous system: Computer experiment

A. E. Galashev, O. R. Rakhmanova, V. N. Tchukanov

Institute of Industrial Ecology Ural Branch of RAS, Ekaterinburg

Abstract: The method of molecular dynamics is used to investigate the effect of absorption of carbon and nitrogen monoxides on the spectral characteristics of a disperse aqueous system. The absorption of $CO$ molecules causes the reduction of the real and imaginary parts of permittivity, and the absorption of $NO$ molecules results in smoothing out of the frequency dependence of these characteristics, which corresponds to that of a system of clusters of pure water. The integral absorptance and reflectance of IR radiation decrease after the attachment of $CO$ molecules to water clusters and undergo insignificant changes as a result of absorption of $NO$ molecules. An increase is observed in the integral power of emission of infrared radiation by disperse aqueous systems which absorbed $CO$ or $NO$ molecules. The clustering of water vapor causes an abrupt reduction of the number of scattering centers and the anti-greenhouse effect.

Full text: PDF file (1136 kB)

English version:
High Temperature, 2009, 47:3, 342–351

Bibliographic databases:

UDC: 535.34:535.233
PACS: 33.20 Ea; 36.40. Vz

Citation: A. E. Galashev, O. R. Rakhmanova, V. N. Tchukanov, “The absorption of carbon and nitrogen monoxides by ultradisperse aqueous system: Computer experiment”, TVT, 47:3 (2009), 360–370; High Temperature, 47:3 (2009), 342–351

Citation in format AMSBIB
\Bibitem{GalRakTch09} \by A.~E.~Galashev, O.~R.~Rakhmanova, V.~N.~Tchukanov \paper The absorption of carbon and nitrogen monoxides by ultradisperse aqueous system: Computer experiment \jour TVT \yr 2009 \vol 47 \issue 3 \pages 360--370 \mathnet{http://mi.mathnet.ru/tvt815} \elib{http://elibrary.ru/item.asp?id=12136627} \transl \jour High Temperature \yr 2009 \vol 47 \issue 3 \pages 342--351 \crossref{https://doi.org/10.1134/S0018151X09030079} \isi{http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&DestLinkType=FullRecord&DestApp=ALL_WOS&KeyUT=000268186200006} \elib{http://elibrary.ru/item.asp?id=13604819} \scopus{http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-67650433824} 

• http://mi.mathnet.ru/eng/tvt815
• http://mi.mathnet.ru/eng/tvt/v47/i3/p360

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Citing articles on Google Scholar: Russian citations, English citations
Related articles on Google Scholar: Russian articles, English articles

This publication is cited in the following articles:
1. Galashev A.E., Rakhmanova O.R., “Computer-Assisted Study of Characteristics of Water Clusters in the Presence of Nitrogen Dioxide”, Colloid J., 72:4 (2010), 478–485
2. Galashev A.E., Rakhmanova O.R., “Spectral Characteristics of Water Clusters in the Presence of Nitrogen Dioxide”, Russ. J. Phys. Chem. A, 84:8 (2010), 1364–1368
3. Galashev A.E., “Cluster Mechanism of the Atmosphere Ozone Destruction by Bromine Ions”, Russ. J. Gen. Chem., 81:13 (2011), 2625–2633
4. A. E. Galashev, O. R. Rakhmanova, O. A. Novruzova, “Computational Study of Interaction of Bromine Ions with Clusters $\mathrm{(O}_2)_6$$(\mathrm{H}_2$$\mathrm{O})_{50}$ and $\mathrm{(O}_3)_6$$(\mathrm{H}_2$$\mathrm{O})_{50}$”, High Temperature, 49:4 (2011), 528–538
5. A. E. Galashev, “Molecular dynamics simulation of adsorption of ozone and nitrate ions by water clusters”, High Temperature, 50:2 (2012), 204–213
6. Galashev A.E., “Spectral Characteristics of Water Clusters in the Presence of Nitrate Ions”, Colloid J., 74:6 (2012), 655–662