Characterization of the structure of ultradispersed diamond using X-ray diffractometry and small-angle X-ray scattering

Two samples of detonation-synthesized ultradispersed diamond have been studied using X-ray diffractometry and small-angle X-ray scattering. It has been shown based on the X-ray diffractometry data that two samples contain regions with both the diamond and graphite-like lattices. Grain radii inside both samples are evaluated from the small-angle scattering data as 30–50 nm. The samples also contain low-dimensional components. A broad Bragg peak corresponding to a set of interplanar distances from 5 to 15 nm is revealed in the small-angle scattering curve of sample no. 1. A structural model of ultradispersed diamond particles, which represents the diamond core surrounded by concentric graphite shells similar to the onionskin, is confirmed.