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This article is cited in 1 scientific paper (total in 1 paper)
Magnetism
Influence of zeolite water on paramagnetic and ferromagnetic resonances in the Co$_2$[Nb(CN)$_8$] $\cdot$ 8H$_2$O molecular magnet
A. I. Dmitrieva, O. V. Koplaka, M. V. Kirmana, H. Tokorob, S. Ohkoshib, R. B. Morgunova a Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow region
b The University of Tokyo,
Tokyo, Japan
Abstract:
The contributions of Co$^{2+}$ and Nb$^{4+}$ ions to the high-frequency dynamic magnetic susceptibility of the Co$_2$[Nb(CN)$_8$] $\cdot$ 8H$_2$O molecular magnet in the paramagnetic state at $T >$ 12 K are separated. It is found that the ferromagnetic ordering, which leads to the reconstruction of the electron paramagnetic resonance spectrum into the ferromagnetic resonance spectrum, occurs at $T <$ 12 K. The influence of zeolite water on the spectra of the paramagnetic and ferromagnetic resonances is found. Dehydration leads to a decrease in the time of the spin relaxation of the ferromagnetic system from 50 ps to 17 ps at $T$ = 4 K and to the variation in the temperature dependences of the widths of the lines and g factors in the electron spin resonance spectra.
Received: 21.02.2013
Citation:
A. I. Dmitriev, O. V. Koplak, M. V. Kirman, H. Tokoro, S. Ohkoshi, R. B. Morgunov, “Influence of zeolite water on paramagnetic and ferromagnetic resonances in the Co$_2$[Nb(CN)$_8$] $\cdot$ 8H$_2$O molecular magnet”, Fizika Tverdogo Tela, 55:8 (2013), 1552–1556; Phys. Solid State, 55:8 (2013), 1663–1667
Linking options:
https://www.mathnet.ru/eng/ftt12515 https://www.mathnet.ru/eng/ftt/v55/i8/p1552
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