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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2012, Volume 95, Issue 7, Pages 435–439
(Mi jetpl2478)
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This article is cited in 10 scientific papers (total in 10 papers)
CONDENSED MATTER
Percolation model of an insulator-conductor transition in ultrananocrystalline diamond films
I. I. Vlasova, M. V. Kanzyubaa, A. A. Shiryaevb, V. V. Volkovc, V. G. Ral'chenkoa, V. I. Konova a A. M. Prokhorov General Physics Institute, Russian Academy of Sciences
b Institute of Physical Chemistry and Electro Chemistry, Russian Academy of Sciences, Moscow
c Institute of Cristallography RAS
Abstract:
A percolation model has been proposed to explain an insulator-conductor transition in ultrananocrystalline diamond films upon addition of nitrogen to a gas mixture used to synthesize films. An observed jump of the conductivity by 10–12 orders of magnitude is a result of the rearrangement of the structure of films leading to the formation of diamond nanorods in a graphite shell. A nitriding-induced increase in the volume fraction of these nanorods (up to 0.22) has been determined from small-angle X-ray scattering data. Conduction occurs through graphite shells and the percolation threshold corresponds to the volume fraction of conducting nanorods of 0.06.
Received: 26.12.2011 Revised: 27.02.2012
Citation:
I. I. Vlasov, M. V. Kanzyuba, A. A. Shiryaev, V. V. Volkov, V. G. Ral'chenko, V. I. Konov, “Percolation model of an insulator-conductor transition in ultrananocrystalline diamond films”, Pis'ma v Zh. Èksper. Teoret. Fiz., 95:7 (2012), 435–439; JETP Letters, 95:7 (2012), 391–395
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https://www.mathnet.ru/eng/jetpl2478 https://www.mathnet.ru/eng/jetpl/v95/i7/p435
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