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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2015, Volume 102, Issue 7, Pages 502–506
DOI: https://doi.org/10.7868/S0370274X15190091 (Mi jetpl4750) 		 
This article is cited in 14 scientific papers (total in 14 papers)

CONDENSED MATTER

Transformation of the structure in a series of mixed K$_2$Ni$_x$Co$_{1-x}$(SO$_4)_2\cdot6$H$_2$O single crystals

N. A. Vasil'eva, N. I. Sorokina, A. M. Antipin, I. A. Verin, A. E. Voloshin

Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia
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DOI: https://doi.org/10.7868/S0370274X15190091
Abstract: The structure of crystals of solid solutions K$_2$Ni$_x$Co$_{1-x}$(SO$_4)_2\cdot6$H$_2$O has been studied. The substitution of nickel atoms for cobalt atoms in the K$_2$Co(SO$_4)_2\cdot6$Н$_2$О structure leads to a decrease in all interatomic distances (Co,Ni)–O. However, the decrease in one of them with the increase in the Ni concentration is smaller than that in the other two. As a consequence, CoO$_6$ octahedra are more distorted than NiO$_6$. Syntheses of the difference electron density show that the structures of crystals of solid solutions K$_2$Co(SO$_4)_2\cdot6$H$_2$O contain more uninterpreted peaks of the residual electron density than the K$_2$Ni(SO$_4)_2\cdot6$H$_2$O structure, indicating a change in the character of the hydrogen bond.
Received: 10.08.2015
English version:
Journal of Experimental and Theoretical Physics Letters, 2015, Volume 102, Issue 7, Pages 448–451
DOI: https://doi.org/10.1134/S0021364015190169
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: N. A. Vasil'eva, N. I. Sorokina, A. M. Antipin, I. A. Verin, A. E. Voloshin, “Transformation of the structure in a series of mixed K$_2$Ni$_x$Co$_{1-x}$(SO$_4)_2\cdot6$H$_2$O single crystals”, Pis'ma v Zh. Èksper. Teoret. Fiz., 102:7 (2015), 502–506; JETP Letters, 102:7 (2015), 448–451
Citation in format AMSBIB
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\paper Transformation of the structure in a series of mixed K$_2$Ni$_x$Co$_{1-x}$(SO$_4)_2\cdot6$H$_2$O single crystals
\jour Pis'ma v Zh. \`Eksper. Teoret. Fiz.
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\vol 102
\issue 7
\pages 502--506
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\jour JETP Letters
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    • This publication is cited in the following 14 articles:
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