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Physical science of materials
Crystals of the phenazine coordination polymer with the third order symmetry axis: formation, properties
M. E. Kompana, V. G. Malyshkina, M. E. Boikoa, M. D. Sharkova, I. Yu. Sapurinab, M. A. Shishovbc a Ioffe Institute, St. Petersburg, Russia
b Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia
c Peter the Great St. Petersburg Polytechnic University, 195251 St. Petersburg, Russia
Abstract:
Unusual quasi-two-dimensional crystals of a regular triangular shape, self-formed in the process of obtaining a coordination polymer based on phenazine and silver, are described and studied. X-ray diffraction studies were carried out, the interplanar distance was determined, and the spectra of Raman scattering were obtained. A mechanism is proposed that can cause the appearance of triangular crystals from nuclei of hexagonal symmetry.
Keywords:
X-ray diffractometry, Raman scattering, phenazines – organic crystals.
Received: 17.12.2021 Revised: 15.02.2022 Accepted: 14.03.2022
Citation:
M. E. Kompan, V. G. Malyshkin, M. E. Boiko, M. D. Sharkov, I. Yu. Sapurina, M. A. Shishov, “Crystals of the phenazine coordination polymer with the third order symmetry axis: formation, properties”, Zhurnal Tekhnicheskoi Fiziki, 92:6 (2022), 815–821
Linking options:
https://www.mathnet.ru/eng/jtf7363 https://www.mathnet.ru/eng/jtf/v92/i6/p815
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