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Mendeleev Communications, 2021, Volume 31, Issue 6, Pages 784–788
DOI: https://doi.org/10.1016/j.mencom.2021.11.005
(Mi mendc1042)
 

This article is cited in 20 scientific papers (total in 20 papers)

Communications

Novel organic magnet derived from pyrazine-fused furazans

V. I. Ovcharenkoab, A. B. Sheremeteva, K. V. Strizhenkoa, S. V. Fokinb, G. V. Romanenkob, A. S. Bogomyakovab, V. A. Morozovb, M. A. Syroeshkina, A. Ya. Kozmenkovaa, A. V. Lalova, M. P. Egorova

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Abstract: The first organic magnet based on a high-nitrogen framework of pyrazine-fused furazans Na(L•−)(H2O)3 was found. A quantum-chemical study of M(L•−)(H2O)n, where M = Li, Na, K, Rb, NH4, revealed that exchange coupling energy between the neighboring radical anions proved highly sensitive to the motion of one L•− relative to another.
Keywords: bis(furazano)pyrazine, sodium, potassium, rubidium, ammonium, stable radical, molecular magnet, McConnell’s exchange model.
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Document Type: Article
Language: English
Video records:
Video_2.mp4 (5.9 Mb)
Supplementary materials:
Supplementary_data_1.pdf (2.4 Mb)


Citation: V. I. Ovcharenko, A. B. Sheremetev, K. V. Strizhenko, S. V. Fokin, G. V. Romanenko, A. S. Bogomyakov, V. A. Morozov, M. A. Syroeshkin, A. Ya. Kozmenkova, A. V. Lalov, M. P. Egorov, “Novel organic magnet derived from pyrazine-fused furazans”, Mendeleev Commun., 31:6 (2021), 784–788
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  • https://www.mathnet.ru/eng/mendc/v31/i6/p784
  • This publication is cited in the following 20 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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