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Mendeleev Communications, 2021, Volume 31, Issue 6, Pages 792–794
DOI: https://doi.org/10.1016/j.mencom.2021.11.007
(Mi mendc1044)
 

This article is cited in 11 scientific papers (total in 11 papers)

Communications

Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans

N. E. Leonova, F. M. Sidorovab, M. S. Klenova, A. M. Churakova, Yu. A. Strelenkoa, A. N. Pivkinac, I. V. Fedyaninde, D. B. Lempertf, T. S. Kon'kovac, Yu. N. Matyushinc, V. A. Tartakovskya

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
d G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
e A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
f Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
Abstract: Three novel energetic furazans with a cyano-NNO-azoxy group were synthesized using cyanamide and 2,2,2-tri- fluoro-N-(4-nitrosofurazan-3-yl)acetamide as the starting compounds. (Cyano-NNO-azoxy)furazans obtained display high experimental enthalpies of formation (+742 to +1073 kcal kg−1), good thermal stability (Tonset = 193–222 °C) and moderate mechanical sensitivity. These compounds may be of interest as energetic fillers in solid fuels for ramjet engines and in solid composite propellants.
Keywords: azoxy compounds, cyano compounds, furazans, combustion calorimetry, enthalpy of formation, differential scanning calorimetry, X-ray diffraction analysis.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (3.3 Mb)


Citation: N. E. Leonov, F. M. Sidorov, M. S. Klenov, A. M. Churakov, Yu. A. Strelenko, A. N. Pivkina, I. V. Fedyanin, D. B. Lempert, T. S. Kon'kova, Yu. N. Matyushin, V. A. Tartakovsky, “Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans”, Mendeleev Commun., 31:6 (2021), 792–794
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  • https://www.mathnet.ru/eng/mendc1044
  • https://www.mathnet.ru/eng/mendc/v31/i6/p792
  • This publication is cited in the following 11 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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