A. S. Abel, A. D. Kharlamova, A. D. Averin, I. P. Beletskaya, “Photoredox-copper catalyzed Meerwein cyanoarylation of styrenes”, Mendeleev Commun., 31:6 (2021), 815

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Mendeleev Communications, 2021, Volume 31, Issue 6, Pages 815–817
DOI: https://doi.org/10.1016/j.mencom.2021.11.015 (Mi mendc1052)

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Photoredox-copper catalyzed Meerwein cyanoarylation of styrenes

A. S. Abel^a, A. D. Kharlamova^a, A. D. Averin^ab, I. P. Beletskaya^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (2989 kB) Citations (5) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.11.015

Graphic abstract: Photoredox-copper catalyzed Meerwein cyanoarylation of styrenes

Abstract: A new procedure for the cyanoarylation of styrenes with arenediazonium salts and Bu₄NCN employs double catalytic system Eosyn Y/Cu(OAc)₂ under the irradiation with green light (530 nm). In the case of diazonium salts bearing electron withdrawing substituents, the products are formed in 40–65% yields. The relative thiocyanatoarylation proceeds only in the presence of photocatalyst, but the Cu(OAc)₂ additive allows for the product yield improvement

Keywords: cyanation, photocatalysis, copper catalysis, Meerwein arylation, styrenes, diazonium salts.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.1 Mb)

Citation: A. S. Abel, A. D. Kharlamova, A. D. Averin, I. P. Beletskaya, “Photoredox-copper catalyzed Meerwein cyanoarylation of styrenes”, Mendeleev Commun., 31:6 (2021), 815–817

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https://www.mathnet.ru/eng/mendc1052

https://www.mathnet.ru/eng/mendc/v31/i6/p815

This publication is cited in the following 5 articles:

Citing articles in Google Scholar: Russian citations, English citations
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