A. I. Fedulin, A. V. Churakov, K. V. Zaitsev, “Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands”, Mendeleev Commun., 31:6 (2021), 847

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Mendeleev Communications, 2021, Volume 31, Issue 6, Pages 847–849
DOI: https://doi.org/10.1016/j.mencom.2021.11.026 (Mi mendc1063)

This article is cited in 4 scientific papers (total in 4 papers)

Communications

Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands

A. I. Fedulin^a, A. V. Churakov^b, K. V. Zaitsev^ac

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (3109 kB) Citations (4) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2021.11.026

Graphic abstract: Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine S<u>N</u>S-ligands

Abstract: New SNS-ligands were obtained by consequent ring-opening of substituted thiiranes by lithiated 2,6-lutidine, mono- functionalized SN-ligands having been isolated as the intermediate compounds. The molecular structure of ligand 2,6-Py(CH₂CH₂CBn₂SH)₂ was elucidated by XRD analysis.The reaction of AlMe₃ with SNS-ligands afforded monomeric methyl aluminum complexes which have been tested in ring- opening polymerization of ε caprolactone in bulk.

Keywords: organoaluminum compounds, thiiranes, SNS-polydentate ligands, methyl aluminum complexes, ring-opening of thiiranes, ring-opening polymerization of lactones.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.2 Mb)

Citation: A. I. Fedulin, A. V. Churakov, K. V. Zaitsev, “Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands”, Mendeleev Commun., 31:6 (2021), 847–849

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https://www.mathnet.ru/eng/mendc/v31/i6/p847

This publication is cited in the following 4 articles:

Citing articles in Google Scholar: Russian citations, English citations
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