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Mendeleev Communications, 2021, Volume 31, Issue 6, Pages 853–855
DOI: https://doi.org/10.1016/j.mencom.2021.11.028
(Mi mendc1065)
 

This article is cited in 28 scientific papers (total in 28 papers)

Communications

Significant impact of lanthanide contraction on the structure of the phenanthroline complexes

P. S. Lemporta, M. V. Evsiuninaa, Yu. V. Nelyubinab, K. L. Isakovskayabc, V. N. Khrustalevde, V. S. Petrova, A. S. Pozdeeva, P. I. Matveeva, Yu. A. Ustynyuka, V. G. Nenajdenkoa

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
d N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
e Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
Abstract: The structure of La, Nd, Eu and Lu complexes with N,N,N',N'-tetrabutyl-1,10-phenanthroline-2,9-dicarbox- amide ligand was examined using X-ray diffraction analysis. Due to the effect of lanthanide contraction, lutetium forms unique type of complex having the coordination number 9 in contrast to other 10-coordinated lanthanides.
Keywords: phenanthrolinediamide, polydentate ligand, lanthanide, complex, lutetium complexes, X-ray, coordination number.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.0 Mb)


Citation: P. S. Lemport, M. V. Evsiunina, Yu. V. Nelyubina, K. L. Isakovskaya, V. N. Khrustalev, V. S. Petrov, A. S. Pozdeev, P. I. Matveev, Yu. A. Ustynyuk, V. G. Nenajdenko, “Significant impact of lanthanide contraction on the structure of the phenanthroline complexes”, Mendeleev Commun., 31:6 (2021), 853–855
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  • This publication is cited in the following 28 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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