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Mendeleev Communications, 2021, Volume 31, Issue 6, Pages 856–858
DOI: https://doi.org/10.1016/j.mencom.2021.11.029
(Mi mendc1066)
 

This article is cited in 6 scientific papers (total in 6 papers)

Communications

Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization

V. G. Fedoseeva, E. A. Verochkina, L. I. Larina, E. V. Kondrashov, I. B. Rosentsveig, N. V. Vchislo

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Abstract: An efficient synthesis of new (Z,E)-2-(alkylthio)alk-2-en-4-ynals by aldol condensation reaction of ynals with (alkylthio)-acetaldehydes using NaOH/DMF system has been developed.The reaction of these products with N,N-diphenylethylene-diamine and p-tosylmethyl isocyanide proceeds at the carbonyl group to form the corresponding imidazolidine and oxazole derivatives.
Keywords: Α-enals, enynals, aldol condensation, heterocyclization, oxazoles, imidazolidines, organogermanium compounds.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (2.5 Mb)


Citation: V. G. Fedoseeva, E. A. Verochkina, L. I. Larina, E. V. Kondrashov, I. B. Rosentsveig, N. V. Vchislo, “Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization”, Mendeleev Commun., 31:6 (2021), 856–858
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  • https://www.mathnet.ru/eng/mendc/v31/i6/p856
  • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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