Abstract:
The reaction of gold(i) chloride with two molecules of 1,5-diaza-3,7-diphosphacyclooctane derivative causes their reorganization into 16-membered macrocyclic tetraphosphine ligand. The structure of the trinuclear gold(i) complex obtained was confirmed by X-ray analysis. The dynamic equilibrium between dinuclear gold(i) complexes with eight-membered cyclic ligands and the trinuclear gold(i) complex with 16-membered ones has been revealed.
Citation:
I. D. Strelnik, I. R. Dayanova, T. M. Poryvaev, T. P. Gerasimova, I. A. Litvinov, S. A. Katsyuba, E. I. Musina, A. A. Karasik, O. G. Sinyashin, “Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template”, Mendeleev Commun., 30:1 (2020), 40–42
Linking options:
https://www.mathnet.ru/eng/mendc1094
https://www.mathnet.ru/eng/mendc/v30/i1/p40
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