T. M. Fedorova, V. M. Derkacheva, E. N. Shevchenko, E. A. Luk'yanets, E. B. Bordaev, O. L. Kaliya, “Hydroxylation of aromatic amines with dioxygen in photooxidation sensitized by substituted phthalocyanines”, Mendeleev Commun., 30:1 (2020), 64

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Mendeleev Communications, 2020, Volume 30, Issue 1, Pages 64–66
DOI: https://doi.org/10.1016/j.mencom.2020.01.021 (Mi mendc1102)

This article is cited in 3 scientific papers (total in 3 papers)

Communications

Hydroxylation of aromatic amines with dioxygen in photooxidation sensitized by substituted phthalocyanines

T. M. Fedorova^a, V. M. Derkacheva^a, E. N. Shevchenko^a, E. A. Luk'yanets^a, E. B. Bordaev^b, O. L. Kaliya^b

^a Russian Research Centre 'Research Institute of Organic Intermediates and Dyes', Moscow, Russian Federation
^b M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation

Full-text PDF (268 kB) Citations (3)

DOI: https://doi.org/10.1016/j.mencom.2020.01.021

Graphic abstract: Hydroxylation of aromatic amines with dioxygen in photooxidation sensitized by substituted phthalocyanines

Abstract: Photooxidation of aniline and its methyl and chloro derivatives with dioxygen sensitized by substituted zinc (PcZn) and palladium (PcPd) phthalocyanines in solution and on the carrier surface upon visible light irradiation affords selectively the corresponding p-aminophenols. Active and the most stable PcPd derivative adsorbed on Amberlite XAD 7HP provides conversion of 2,6-dimethylaniline with selectivity over 90% without the loss of sensitizer activity at least in 8 repeated cycles, the overall turnover number of the sensitizer being greater than 25,000.

Keywords: photooxidation, singlet oxygen, arylamines, sensitizers, photocatalysis, hydroxylation, p-aminophenols, phthalocyanines.

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Document Type: Article

Language: English

Citation: T. M. Fedorova, V. M. Derkacheva, E. N. Shevchenko, E. A. Luk'yanets, E. B. Bordaev, O. L. Kaliya, “Hydroxylation of aromatic amines with dioxygen in photooxidation sensitized by substituted phthalocyanines”, Mendeleev Commun., 30:1 (2020), 64–66

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https://www.mathnet.ru/eng/mendc1102

https://www.mathnet.ru/eng/mendc/v30/i1/p64

This publication is cited in the following 3 articles:

Citing articles in Google Scholar: Russian citations, English citations
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