M. V. Moskalev, D. A. Razborov, A. A. Bazanov, V. G. Sokolov, T. S. Koptseva, E. V. Baranov, I. L. Fedushkin, “One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand”, Mendeleev Commun., 30:1 (2020), 94

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Mendeleev Communications, 2020, Volume 30, Issue 1, Pages 94–96
DOI: https://doi.org/10.1016/j.mencom.2020.01.031 (Mi mendc1112)

This article is cited in 15 scientific papers (total in 15 papers)

Communications

One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand

M. V. Moskalev, D. A. Razborov, A. A. Bazanov, V. G. Sokolov, T. S. Koptseva, E. V. Baranov, I. L. Fedushkin

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Full-text PDF (816 kB) Citations (15) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2020.01.031

Graphic abstract: One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand

Abstract: Treatment of a bulky dbhmp-bian ligand (dbhmp-bian==1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) by 1 equiv. of LiAlH₄ or mixture of 3/4 equiv. LiAlH₄ and 1/3 eqiuv. AlCl₃ in tetrahydrofuran results in new hydrides [(dbhmp-bian)AlH2(THF)]^-[Li(THF)₄]⁺ and (dbhmp-bian)AlH(THF), respectively. Both complexes were characterized by spectroscopic (IR, NMR) and X-ray diffraction methods.

Keywords: aluminum hydrides, imines, acenaphthenes, sterically hindered ligands, diimine ligands, redox-active ligands.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.0 Mb)

Citation: M. V. Moskalev, D. A. Razborov, A. A. Bazanov, V. G. Sokolov, T. S. Koptseva, E. V. Baranov, I. L. Fedushkin, “One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand”, Mendeleev Commun., 30:1 (2020), 94–96

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https://www.mathnet.ru/eng/mendc/v30/i1/p94

This publication is cited in the following 15 articles:

Citing articles in Google Scholar: Russian citations, English citations
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