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Mendeleev Communications, 2020, Volume 30, Issue 2, Pages 139–141
DOI: https://doi.org/10.1016/j.mencom.2020.03.002
(Mi mendc1126)
 

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes

A. A. Konnova, M. S. Klenova, A. M. Churakova, Yu. A. Strelenkoa, K. A. Lyssenkob, V. A. Tartakovskya

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract: Synthesis of the first amino- and formylamino-1,3a,4,6atetraazapentalenes via thermolysis of the corresponding 4-amino- and 4-formylamino-2-(2-azidophenyl)-2H-[1,2,3]triazoles has been elaborated. The crystal structures of 2-amino-3-(tert-butyl-NNO-azoxy)-1H-[1,2,3]triazolo[2,1-a][1,2,3]benzotriazol-1-id-4-ium and 3-amino-2-(tert-butyl-NNO-azoxy)-1H-[1,2,3]triazolo[2,1-a][1,2,3]benzotriazol-1-id4-ium have been established using X-ray diffraction analysis.
Keywords: tetraazapentalenes, 1,2,3-triazoles, azides, cyclization, X-ray, differential scanning calorimetry.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (5.1 Mb)


Citation: A. A. Konnov, M. S. Klenov, A. M. Churakov, Yu. A. Strelenko, K. A. Lyssenko, V. A. Tartakovsky, “Synthesis and crystal structure of the first amino-1,3a,4,6a-tetraazapentalenes”, Mendeleev Commun., 30:2 (2020), 139–141
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  • https://www.mathnet.ru/eng/mendc/v30/i2/p139
  • This publication is cited in the following 2 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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