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Mendeleev Communications, 2020, Volume 30, Issue 2, Pages 142–144
DOI: https://doi.org/10.1016/j.mencom.2020.03.003
(Mi mendc1127)
 

This article is cited in 13 scientific papers (total in 13 papers)

Communications

Assembly of annulated 1,3-diazapyrenes by consecutive cross-coupling and cyclodehydrogenation of (het)arene moieties

E. V. Verbitskiyab, E. M. Dinastiyaa, O. S. Eltsovab, E. F. Zhilinaa, A. V. Shchepochkinab, G. L. Rusinovab, O. N. Chupakhinab, V. N. Charushinab

a I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
b Institute of Chemical Engineering, Ural Federal University, Ekaterinburg, Russian Federation
Abstract: Di(het)areno[e,l][1,3]diazapyrene core was constructed by FeCl3-mediated intramolecular oxidative cyclodehydrogenation of 5-[2,6-di(het)arylphenyl]pyrimidine precursors, which in turn were obtained by the Suzuki cross-coupling of 5-(2,6-dibromophenyl)pyrimidine derivative with the corresponding (het)arylboronic acids. Molecular orbital calculations as well as redox and photophysical measurements show that the fused products are promising for organic electronic application.
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Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (2.2 Mb)


Citation: E. V. Verbitskiy, E. M. Dinastiya, O. S. Eltsov, E. F. Zhilina, A. V. Shchepochkin, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin, “Assembly of annulated 1,3-diazapyrenes by consecutive cross-coupling and cyclodehydrogenation of (het)arene moieties”, Mendeleev Commun., 30:2 (2020), 142–144
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  • https://www.mathnet.ru/eng/mendc/v30/i2/p142
  • This publication is cited in the following 13 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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