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Mendeleev Communications, 2020, Volume 30, Issue 2, Pages 162–164
DOI: https://doi.org/10.1016/j.mencom.2020.03.010
(Mi mendc1134)
 

This article is cited in 12 scientific papers (total in 12 papers)

Communications

A panchromatic pyrazine-fused porphyrin dimer

I. A. Abdulaevaa, D. A. Polivanovskaiaa, K. P. Birina, Yu. G. Gorbunovaab, A. Yu. Tsivadzeab

a A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: New pyrazine-fused porphyrin dimer was unexpectedly produced by mild oxidation of [2,3-diamino-5,10,15,20-tetrakis(4-butoxyphenyl)porphyrinato]nickel(ii) in 40% yield. The obtained porphyrin dimer demonstrates bathochromic shift of absorption bands compared to the reported analogues, along with panchromatic absorption in the 250–650nm range, which is promising for optical, photovoltaic and medical applications.
Keywords: pyrazine-fused dimers, porphyrins, diamines, oxidation, nickel complexes, panchromatic absorption.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.1 Mb)


Citation: I. A. Abdulaeva, D. A. Polivanovskaia, K. P. Birin, Yu. G. Gorbunova, A. Yu. Tsivadze, “A panchromatic pyrazine-fused porphyrin dimer”, Mendeleev Commun., 30:2 (2020), 162–164
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  • https://www.mathnet.ru/eng/mendc/v30/i2/p162
  • This publication is cited in the following 12 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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