K. Yu. Monakhov, W. Wernsdorfer, “A cubane-type nickel single-molecule magnet with exchange-biased quantum tunneling of magnetization”, Mendeleev Commun., 30:2 (2020), 168

Mendeleev Communications

RUS ENG

JOURNALS PEOPLE ORGANISATIONS CONFERENCES SEMINARS VIDEO LIBRARY PACKAGE AMSBIB

JavaScript is disabled in your browser. Please switch it on to enable full functionality of the website

	General information
	Latest issue
	Archive

	Search papers
	Search references

	RSS
	Latest issue
	Current issues
	Archive issues
	What is RSS

Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
	Find

Personal entry:
Login:
Password:
	Save password
	Enter
	Forgotten password?
	Register

Mendeleev Communications, 2020, Volume 30, Issue 2, Pages 168–170
DOI: https://doi.org/10.1016/j.mencom.2020.03.012 (Mi mendc1136)

This article is cited in 2 scientific papers (total in 2 papers)

Communications

A cubane-type nickel single-molecule magnet with exchange-biased quantum tunneling of magnetization

K. Yu. Monakhov^a, W. Wernsdorfer^bc

^a Leibniz Institute of Surface Engineering (IOM), Leipzig, Germany
^b Physikalisches Institut, Karlsruhe Institute of Technology, Karlsruhe, Germany
^c Institute of Nanotechnology, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, Germany

Full-text PDF (859 kB) Citations (2)

DOI: https://doi.org/10.1016/j.mencom.2020.03.012

Graphic abstract: A cubane-type nickel single-molecule magnet with exchange-biased quantum tunneling of magnetization

Abstract: Low temperature magnetization measurements were performed on single crystals of the pyridyl-alcohol-supported [Ni(μ₃-Cl)Cl(HL·S)]₄ coordination cluster and they revealed open hysteresis loops up to 30mK at a sweep rate of 0.07Ts⁻¹. The studied molecule with intramolecular ferromagnetic coupling J_intra of 15.251K (+10.6cm⁻¹) is an exchange-biased single-molecule magnet that exhibits intermolecular antiferromagnetic coupling J_inter of −0.004K (−0.003cm⁻¹) in the supramolecular environment of four other cubane-type units. Quantum tunneling of magnetization characterized by five steps at −0.1, −0.05, 0, 0.05 and 0.1T was observed.

Keywords: nickel, tetranuclear metal complex, single-crystal measurements, magnetism, intermolecular exchange coupling.

Bibliographic databases:

Document Type: Article

Language: English

Citation: K. Yu. Monakhov, W. Wernsdorfer, “A cubane-type nickel single-molecule magnet with exchange-biased quantum tunneling of magnetization”, Mendeleev Commun., 30:2 (2020), 168–170

Linking options:

https://www.mathnet.ru/eng/mendc1136

https://www.mathnet.ru/eng/mendc/v30/i2/p168

This publication is cited in the following 2 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Registration to the website

Logotypes