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Mendeleev Communications, 2020, Volume 30, Issue 2, Pages 223–225
DOI: https://doi.org/10.1016/j.mencom.2020.03.031
(Mi mendc1155)
 

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid

M. N. Elinsona, A. N. Vereshchagina, Yu. E. Ryzhkovaa, S. K. Krymovab, N. A. Leonovaab, A. S. Goloveshkinc, M. P. Egorova

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Electrocatalytic transformation of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid in alcohols occurs in an undivided cell in the presence of sodium halides, selectively affording substituted 4-{[3-hydroxy-6-(hydroxymethyl)-4-oxo-4H-pyran-2-yl](aryl)methyl}-5-methyl-1,2-dihydro-3Hpyrazol-3-ones in 73–95% yields and with 240–320% current efficiency. The multicomponent process provides a facile and efficient way to the new type of systems with heterocyclic moieties separated by aryl-substituted C-spacer. The product structure has been confirmed by X-ray diffraction data
Keywords: electrocatalysis, multicomponent process, tandem reaction, aldehydes, 2,4-dihydro-3H-pyrazol-3-one, kojic acid.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (3.5 Mb)


Citation: M. N. Elinson, A. N. Vereshchagin, Yu. E. Ryzhkova, S. K. Krymov, N. A. Leonova, A. S. Goloveshkin, M. P. Egorov, “Electrocatalytic one-pot multicomponent assembly of aldehydes, 2,4-dihydro-3H-pyrazol-3-ones and kojic acid”, Mendeleev Commun., 30:2 (2020), 223–225
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  • https://www.mathnet.ru/eng/mendc/v30/i2/p223
  • This publication is cited in the following 7 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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