Abstract:
Complexation of 5-(4-dimethylaminophenyl)-1-phenylthiocarbamoyl-3-(pyridin-2-yl)-4,5-dihydro-1H-pyrazole with CuCl2 followed by recrystallization from alcohols as external nucleophiles affords the products of pyrazoline ring opening by thiosemicarbazone moiety. The structure of the obtained complex was confirmed by X-ray diffraction data.
Keywords:
copper(ii) complexes, thiosemicarbazone complexes, pyrazolines, ring opening, alcohols, X-ray.
Citation:
N. I. Vorozhtsov, D. D. Korablina, L. A. Sviridova, V. A. Tafeenko, A. A. Moiseeva, N. V. Zyk, E. K. Beloglazkina, “Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride”, Mendeleev Commun., 30:2 (2020), 244–245
Linking options:
https://www.mathnet.ru/eng/mendc1163
https://www.mathnet.ru/eng/mendc/v30/i2/p244
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