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Mendeleev Communications, 2020, Volume 30, Issue 2, Pages 246–248
DOI: https://doi.org/10.1016/j.mencom.2020.03.040
(Mi mendc1164)
 

This article is cited in 11 scientific papers (total in 11 papers)

Communications

Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole

V. I. Smirnova, L. M. Sinegovskayaa, L. N. Parshinaa, A. V. Artem'evbc, I. V. Sterkhovaa

a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
c Novosibirsk State University, Novosibirsk, Russian Federation
Abstract: Two new manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole were synthesized and characterized by single crystal X-ray diffraction analysis, UV-VIS and IR spectroscopy. Their structures were compared with those of related copper(ii) and cobalt(ii) complexes. In the case of copper complex, the coordination site formed by hexafluoroacetylacetonate at the Cu2+ ion and nitrogen atoms of the two vinylimidazole cycles is slightly distorted, while in all the other considered complexes, this distortion is insignificant.
Keywords: metal complexes, hexafluoroacetylacetonates, crystal structure, X-ray, UV-VIS spectra.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (600.5 Kb)


Citation: V. I. Smirnov, L. M. Sinegovskaya, L. N. Parshina, A. V. Artem'ev, I. V. Sterkhova, “Copper(ii), cobalt(ii), manganese(ii) and nickel(ii) bis(hexafluoroacetylacetonate) complexes with N-vinylimidazole”, Mendeleev Commun., 30:2 (2020), 246–248
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  • https://www.mathnet.ru/eng/mendc1164
  • https://www.mathnet.ru/eng/mendc/v30/i2/p246
  • This publication is cited in the following 11 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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